Synthesis and characterization of green rust-deposited MoS composites for adsorptive removal of EDTA-chelated Ni(II) in wastewater.

Ethylenediamminetetraacetatonickel(II) (EDTA-Ni(II)) has emerged as a significant soil and groundwater contaminant due to the increasing agricultural and industrial activities, posing environmental challenges. This study focuses on addressing the reactivity of green rust (GR), which can be hindered by oxidation with oxygen, limiting its effectiveness in remediation processes. To overcome this limitation and enhance the adsorptive capacities, the combination of sulfate green rust (SO-GR) with various Fe(II)/Fe(III) ratios with a high-surface-area adsorbent, MoS, resulting in the formation of binary composites of green rust-deposited MoS (MSGs) were explored. The aim was to improve the removal efficiency of EDTA-Ni(II) from contaminated wastewater. To characterize the MSGs, a comprehensive analysis using XRD, SEM, TEM, FTIR, and X-ray absorption spectroscopy was performed. The surface areas of the MSGs were smaller than that of MoS but larger than that of the SO-GRs, indicating a promising composite material. XANES spectra analysis revealed that both MSGs and SO-GRs exhibited a mixture of ferrous and ferric ions, as evident from their spectral positioning between FeO and FeO. The optimal pH for efficient removal of EDTA-Ni(II) was 3, which resulted in removal efficiencies of 45.6%, 47.3%, 46.0%, and 46.2% for MSG 1, MSG 2, MSG 3, and MSG 4 after 24 h, respectively. Reducing the initial concentration of EDTA-Ni(II) to 50 mg Ni(II)/L effectively doubled the removal efficiency. Notably, as EDTA-Ni(II) was removed, an increased leaching of iron was observed, leading to a total iron concentration exceeding 40 mg/L for the composites with higher Fe(II)/Fe(III) ratios. These findings underscore the potential of MSG as a promising material for degrading EDTA-Ni(II) in contaminated wastewater, offering a viable solution to mitigate the environmental impact of this emerging contaminant. This study contributes to the understanding of green rust reactivity and provides valuable insights for developing effective strategies to address the challenges associated with EDTA-Ni(II) contamination.