One-step fabrication of vanadium-doped CoFe PBA nanosheets for efficient oxygen evolution reaction.

Dalton Trans

College of Chemistry and Materials Science, The Key Laboratory of Functional Molecular Solids, Ministry of Education, Anhui Laboratory of Molecular-Based Materials, Key Laboratory of Electrochemical Clean Energy of Anhui Higher Education Institutes, Anhui Normal University, Wuhu 241000, P. R. China.

Published: August 2023

Finding effective and affordable non-noble metal catalysts is one of the most important yet difficult tasks because of the sluggish kinetics of the oxygen evolution reaction (OER). Therefore, we synthesized vanadium-doped CoFe PBA nanosheets on nickel foam in a single step to change the electronic structure with metal doping. The sheet structure facilitates charge transfer, while vanadium doping modifies the electronic structure to enhance the catalytic activity. With just a 229 mV overpotential needed in the OER reaction to reach 10 mA cm, the as-synthesised electrocatalyst demonstrates high electrocatalytic activity. The produced electrocatalyst can operate at a current density of 10 mA cm for 12 h, and it displays outstanding stability even at a high OER current density of 100 mA cm for 12 h. This study will contribute to the development of efficient and affordable non-noble metal-based electrocatalysts.

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http://dx.doi.org/10.1039/d3dt01629cDOI Listing

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One-step fabrication of vanadium-doped CoFe PBA nanosheets for efficient oxygen evolution reaction.

Dalton Trans

August 2023

College of Chemistry and Materials Science, The Key Laboratory of Functional Molecular Solids, Ministry of Education, Anhui Laboratory of Molecular-Based Materials, Key Laboratory of Electrochemical Clean Energy of Anhui Higher Education Institutes, Anhui Normal University, Wuhu 241000, P. R. China.

Finding effective and affordable non-noble metal catalysts is one of the most important yet difficult tasks because of the sluggish kinetics of the oxygen evolution reaction (OER). Therefore, we synthesized vanadium-doped CoFe PBA nanosheets on nickel foam in a single step to change the electronic structure with metal doping. The sheet structure facilitates charge transfer, while vanadium doping modifies the electronic structure to enhance the catalytic activity.

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