This study investigated the effect of starch crystallinity on starch reassembly behaviors during the heat-moisture treatment (HMT) using starches with A-type crystal content of 0.00%-19.03%. The results showed that HMT reduced the native starch crystal content from 19.03% to 15.02% and increased starch thermostability, leading to a decrease in rapidly digestible starch (RDS) content from 86.91% to 76.71%. Moreover, starches containing a crystal content of 2.51%-8.11% exhibited significant reassembly during the HMT, and the resulting modified starches had more crystals and less RDS of 63.43%-69.31%. Interestingly, starches lacked A-type crystals but had some helical structures exhibiting A-type crystalline structures and lower digestibility after HMT. These findings verified that starch could significantly reassemble to form crystalline structures during the HMT. Controlling the crystal content of starch granules, particularly between 2.51% and 8.11%, was a promising approach for promoting starch reassembly during HMT and reducing starch digestibility.
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http://dx.doi.org/10.1016/j.foodchem.2023.136966 | DOI Listing |
Polymers (Basel)
January 2025
Department of Forest and Fire Sciences, University of Idaho, Moscow, ID 83844-1132, USA.
This study investigated the valorization of industrial lignin for producing biodegradable polybutylene succinate (PBS)-lignin copolymers. PBS was blended with varying lignin contents (0-45 wt. %) and crosslinked/grafted using dicumyl peroxide (DCP).
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January 2025
Institute of Polymers, Composites and Biomaterials, National Research Council, via Previati n.1/E, 23900 Lecco, Italy.
This study explores the impact of blending polyethylene terephthalate (PET) with polybutylene terephthalate (PBT) on the thermal, structural, and mechanical properties of 3D-printed materials. Comprehensive analyses, including Fourier-transform infrared spectroscopy (FT-IR), thermogravimetric analysis (TGA), X-ray diffraction (XRD), differential scanning calorimetry (DSC), and mechanical testing, were conducted to assess the influence of blend composition. FT-IR confirmed that PET and PBT blend physically without transesterification, while TGA showed enhanced thermal stability with increasing PET content.
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January 2025
Faculty of Food Science and Engineering, Kunming University of Science and Technology, Kunming 650500, China.
The use of biomass feedstocks for producing high-value-added chemicals is gaining significant attention in the academic community. In this study, near-infrared carbon dots (NIR-CDs) with antimicrobial and bioimaging functions were prepared from branches and leaves using a novel green synthesis approach. The spectral properties of the synthesized NIR-CDs were characterized by ultraviolet-visible (UV-Vis) absorption and fluorescence spectroscopy.
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January 2025
Institute of Food Engineering-FoodUPV, Universitat Politècnica de València, 46022 Valencia, Spain.
Almond shells (ASs) are a potential source of cellulose that could be obtained through sustainable methods for their valorisation. Biocomposites (BCs) from polyvinyl alcohol (PVA) and cellulose are interesting materials for developing sustainable packaging materials. BC based on PVA and AS cellulose were obtained by melt blending and compression moulding, by using subcritical water extraction at 160 or 180 °C, and subsequent bleaching with sodium chlorite (C) or hydrogen peroxide (P) to purify cellulose.
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January 2025
Department of Chemical Technology, Institute of Chemical Sciences, Faculty of Chemistry, Maria Curie-Skłodowska University, 3 Maria Curie-Skłodowska Square, 20-031 Lublin, Poland.
The reaction mechanism of soot oxidation on Mn (MnO), Mn-Ce (MnO-CeO), and Ce (CeO) catalysts in tight contact conditions was investigated using ITKA (isotopic transient kinetic analysis). The obtained results suggest that lattice-bulk oxygen from all studied catalysts takes part in the soot oxidation process but with varying relative contributions: for the Ce catalyst, this contribution is practically 100%, whereas with decreasing Ce content in Mn-Ce catalysts, the significance of lattice-bulk oxygen for soot oxidation diminishes. For the Mn catalyst, it is estimated to be below 50%.
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