[NHC → GeN(Ar)CuNAr], the formal adduct of germanium analogue of organic isonitrile [GeNAr] with Cu(I) imide [(CuNAr)] (Ar = 2,6-PrCH) was prepared from the N-heterocyclic carbene (NHC) stabilized acyclic germylene Ge[N(H)Ar] by reacting with two equivalents of BuLi and CuCl(PPh). As elucidated by X-ray crystal structural characterization, the two separated [GeNAr] moieties interacted with [(CuNAr)] core in the side-on mode.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1039/d3dt02094k | DOI Listing |
Publication Analysis
Top Keywords
germanium analogue
8
analogue organic
8
organic isonitrile
8
cui imide
8
side-on mode
8
interaction germanium
4
isonitrile cui
4
imide side-on
4
mode [nhc
4
[nhc →
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!