Three-Dimensional Mass Transfer Modeling of Hydroquinone Adsorption on Biochar.

Toxics

Shanxi Key Laboratory for Research and Development of Regional Plants, School of Life Science, Shanxi University, Taiyuan 030006, China.

Published: July 2023

In this work, the overall adsorption kinetic process of hydroquinone on biochar (PAC) was analyzed in depth. A 3D mass transfer model of pore volume and surface diffusion was established, and the diffusion mechanism was analyzed. The characterization results show PAC has a higher porosity value, which is conducive to the adsorption of hydroquinone. The adsorption process modeling results show that the combined effect of pore volume diffusion and surface diffusion promotes the total diffusion process of hydroquinone in the PAC particles, and the two mechanisms of pore volume and surface diffusion exist simultaneously. Under the different operating concentrations, the range of surface diffusion coefficient D is 2.5 × 10-1.74 × 10 cm/s, and the contribution rate of surface diffusion SDCP% is close to 100%, which is much larger than pore volume diffusion, revealing that regardless of the contact time and position, surface diffusion occupies the main position in intraparticle diffusion.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC10384758PMC
http://dx.doi.org/10.3390/toxics11070639DOI Listing

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