We are proposing a conceptual membrane electrode assembly (MEA) of a proton exchange membrane water electrolyzer that includes a layer of graphene oxide (GO) at the cathode side. This GO layer primarily reinforces the MEA to allow operation at a higher pressure difference between the cathode and anode side. Additional benefits would be that a perfect GO layer would prevent both water and hydrogen crossover and thus would allow for pure, dry hydrogen escaping directly from the electrolyzer without losses due to hydrogen crossover, thus eliminating the need for hydrogen clean-up steps. The mechanical strength of graphene will also allow for a thinner polymer electrolyte membrane and could thus save cost. Finally, the effect of electro-osmotic drag on the water content in such an MEA is discussed, and it is argued that it could lead to an oversaturated membrane, which is highly desirable.
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http://dx.doi.org/10.3390/membranes13070614 | DOI Listing |
Extracell Vesicle
December 2024
Department of Chemical Engineering, University of Puerto Rico-Mayaguez, Route 108, Mayaguez, Puerto Rico, USA.
Matrix-bound vesicles (MBVs), an integral part of the extracellular matrix (ECM), are emerging as pivotal factors in ECM-driven molecular signaling. This study is the first to report the isolation of MBVs from porcine arterial endothelial cell basement membranes (A-MBVs) and thyroid cartilage (C-MBVs), the latter serving as a negative control due to its minimal vascular characteristics. Using Transmission Electron Microscopy (TEM), Nano-Tracking Analysis (NTA), Electrochemical Impedance Spectroscopy (EIS), and Atomic Force Microscopy (AFM), we orthogonally characterized the isolated MBVs.
View Article and Find Full Text PDFAnalyst
January 2025
Department of Applied Chemistry, Faculty of Science and Technology, Keio University, 3-14-1 Hiyoshi, Kohoku-ku, Yokohama, Kanagawa 223-8522, Japan.
A paper-based potentiometric sensor integrated with a polymeric hydrogel has been developed for sodium ion (Na) determination in human urine. The construction of an all-solid-state ion selective electrode (s-ISE) and an all-solid-state reference electrode (s-RE) on a photo paper substrate was achieved using an inkjet printing method. For s-ISE fabrication, carbon nanotubes (CNTs) and gold nanoparticles (AuNPs) were printed on the substrate as a nanocomposite solid contact.
View Article and Find Full Text PDFPolymers (Basel)
January 2025
State Key Laboratory of Precision Manufacturing for Extreme Service Performance, College of Mechanical and Electrical Engineering, Central South University, Changsha 410083, China.
Vibration sensors are integral to a multitude of engineering applications, yet the development of low-cost, easily assembled devices remains a formidable challenge. This study presents a highly sensitive flexible vibration sensor, based on the piezoresistive effect, tailored for the detection of high-dynamic-range vibrations and accelerations. The sensor's design incorporates a polylactic acid (PLA) housing with cavities and spherical recesses, a polydimethylsiloxane (PDMS) membrane, and electrodes that are positioned above.
View Article and Find Full Text PDFPolymers (Basel)
January 2025
School of Chemical Engineering, Yeungnam University, 280 Daehak-ro, Gyeongsan 38541, Republic of Korea.
Solid polymer electrolytes (SPEs) for symmetrical supercapacitors are proposed herein with activated carbon as electrodes and optimized solid polymer electrolyte membranes, which serve as the separators and electrolytes. We propose the design of a low-cost solid polymer electrolyte consisting of guanidinium nitrate (GuN) and poly(ethylene oxide) (PEO) with poly(vinylpyrrolidone) (PVP). Using the solution casting approach, blended polymer electrolytes with varying GuN weight percentage ratios of PVP and PEO are prepared.
View Article and Find Full Text PDFSmall
January 2025
Environment Research Institute, Shandong University, Qingdao, 266237, China.
The direct electrochemical conversion of bicarbonate solutions (i.e., captured CO) has emerged as a sustainable approach for integrating CO capture and utilization compared to the traditional independent and sequential route.
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