Visible light-assisted hydrogen generation from ammonia borane over Z-Scheme NiO-CuO heterostructures.

The design and fabrication of cheap and high-efficiency catalysts for ammonia borane (AB) hydrolysis for hydrogen production is crucial for its commercial applications. Improvement of the catalytic performance of the catalysts with the assistance of sunlight, a costless resource, is extremely attractive. Herein, we have constructed Z-scheme heterostructured V-NiO-CuO catalysts with strong interfacial electronic interactions and abundant oxygen vacancies to enhance hydrogen production from NHBH solution under visible light illumination. The as-prepared V-NiO-CuO catalysts exhibit excellent catalytic activity with a high turnover frequency (TOF) of 35.3 mol mol min toward AB hydrolysis under visible light. It is demonstrated that excellent catalytic performance is highly related to the effective separation and migration of charge on the catalyst surface. As a result, dual active sites were created, making it easier for various reactants to be adsorbed and activated on the catalyst surface. Furthermore, the density functional theory (DFT) calculations indicate that the adsorption and activation of HO occurred mainly at the Ni site of V-NiO-CuO. When the V-NiO-CuO is irradiated with visible light, the photogenerated electrons assembled on the conduction band were transferred to the O atom through the Ni-O bond, which made the bond length of HO molecules longer and OH bonds more prone to breaking, thus facilitating AB hydrolysis under illumination. The findings in this work pave the way to design novel and efficient heterostructured catalysts for fast hydrogen release from NHBH under visible light irradiation.