For the first time, a continuous flow solar photo-Fenton demonstration plant has been assessed for wastewater reclamation according to the EU 2020/741 regulation. The treated water qualities achieved under two operating strategies (acidic and neutral pH) in a 100-m raceway pond reactor were explored in terms of liquid depth, iron source, reagent concentrations, and hydraulic residence time over three consecutive days of operation. The results obtained at acidic pH showed removal percentages of contaminants of emerging concern (CECs) > 75% and water quality classes B, C and D according to EU regulation at both assessed operating conditions, with treatment capacities up to 1.92 m m d. At neutral pH with ferric nitrilotriacetate (Fe-NTA), 50% of CEC removal and only water quality class D were achieved with the most oxidizing condition assessed, giving a treatment capacity of 0.80 m m d. The treatment capacities obtained in this work, which have never been achieved with solar water treatments, demonstrate the potential of this technology for commercial-scale application.
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http://dx.doi.org/10.1016/j.jhazmat.2023.132101 | DOI Listing |
J Environ Manage
January 2025
Solar Energy Research Centre (CIESOL), Joint Centre University of Almería-CIEMAT, Ctra. de Sacramento s/n, Almería, 04120, Spain; Chemical Engineering Department, University of Almería, Carretera de Sacramento s/n, Almería, 04120, Spain.
Model-based tools applied to wastewater management have been identified as an emerging solution to address the associated challenges related to the optimization of the technologies, meeting more restricted water quality standards. Thus, for the first time, the demonstration of the solar photo-Fenton process for microcontaminant removal in the operating environment of a model-based tool is reported. This tool aids in determining the right cost-effective seasonal strategy for a 37-m demonstration-scale photoreactor operating in a rural wastewater treatment plant.
View Article and Find Full Text PDFChem Asian J
December 2024
SN Bose National Centre for Basic Sciences, Condensed Matter and Materials Physics, JD Block, Sector III, 700106, Salt Lake City, INDIA.
Mass-fraction-optimized heterojunction composites featuring precisely engineered interfaces and mesoporous structures are crucial for improving light absorption, minimizing electron-hole recombination, and boosting overall catalytic efficiency. Herein, highly efficient mesoporous-NiFe2O4@g-C3N4 heterojunctions were developed by embedding p-type NiFe2O4 nanoparticles (NPs) within n-type porous ultrathin g-C3N4 (p-uCN) nanosheets. The optimized NiFe2O4@g-C3N4, loaded with 20wt% magnetic counterparts, exhibits exceptional photocatalytic methylene blue degradation, achieving the highest performance in both photocatalytic and photo-Fenton processes with rate constants of 0.
View Article and Find Full Text PDFChemosphere
December 2024
School of Materials Science and Engineering, Shijiazhuang Tiedao University, Hebei Key Laboratory of New Materials for Collaborative Development of Traffic Engineering and Environment. Electronic address:
Nanoscale FeWO/BiVO heterojunctions were directly grown on the graphite fiber felt (GF) with good conductivity to construct a FeWO/BiVO @GF solar photo-Fenton like wastewater treatment system. The removal effect of COD from phenolic wastewater and the mechanism of synergistic improvement of wastewater treatment efficiency by this system were investigated. The FeWO/BiVO heterojunction prepared by hydrothermal method exhibited higher photoelectric conversion efficiency and solar light utilization rate, thus endowing FeWO/BiVO with excellent solar-Fenton like reaction activity.
View Article and Find Full Text PDFWater Res
November 2024
LNEG, National Laboratory of Energy and Geology I.P., Bioenergy and Biorefineries Unit, Estrada do Paço do Lumiar 22, Lisbon 1649-038, Portugal; GreenCoLab, Green Ocean Technologies and Products Collaborative Laboratory, University of Algarve, Campus de Gambelas, Faro 8005-139, Portugal.
Pig farming generates highly polluted wastewater that requires effective treatment to minimize environmental damage. Microalgae can recover nutrients from piggery wastewater (PWW), but excessive nutrient and turbidity levels inhibit their growth. Solar photo-Fenton (PF) offer a sustainable and cost-effective pretreatment to allow microalgal growth for further PWW treatment.
View Article and Find Full Text PDFSmall Methods
November 2024
Ministry of Education Key Laboratory for the Green Preparation and Application of Functional Materials, Hubei University, Wuhan, 430062, P. R. China.
Solar-driven water evaporation is considered as the sustainable approach to alleviate freshwater resource crisis through direct use of solar energy. However, it is still challenging to achieve the multifunctional solar evaporators equipped with both high evaporation and purification performance to handle practical complex wastewater. Here, a simple and cost-effective multifunctional 3D solar evaporator is prepared by alternately decorating the commercial sponge with FeOOH quantum dots (FQDs) supported MXene sheets composites and chitosan hydrogel coatings for enabling the solar water evaporation and organic wastewater photodegradation simultaneously.
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