Severity: Warning
Message: file_get_contents(https://...@gmail.com&api_key=61f08fa0b96a73de8c900d749fcb997acc09): Failed to open stream: HTTP request failed! HTTP/1.1 429 Too Many Requests
Filename: helpers/my_audit_helper.php
Line Number: 143
Backtrace:
File: /var/www/html/application/helpers/my_audit_helper.php
Line: 143
Function: file_get_contents
File: /var/www/html/application/helpers/my_audit_helper.php
Line: 209
Function: simplexml_load_file_from_url
File: /var/www/html/application/helpers/my_audit_helper.php
Line: 3098
Function: getPubMedXML
File: /var/www/html/application/controllers/Detail.php
Line: 574
Function: pubMedSearch_Global
File: /var/www/html/application/controllers/Detail.php
Line: 488
Function: pubMedGetRelatedKeyword
File: /var/www/html/index.php
Line: 316
Function: require_once
Severity: Warning
Message: Attempt to read property "Count" on bool
Filename: helpers/my_audit_helper.php
Line Number: 3100
Backtrace:
File: /var/www/html/application/helpers/my_audit_helper.php
Line: 3100
Function: _error_handler
File: /var/www/html/application/controllers/Detail.php
Line: 574
Function: pubMedSearch_Global
File: /var/www/html/application/controllers/Detail.php
Line: 488
Function: pubMedGetRelatedKeyword
File: /var/www/html/index.php
Line: 316
Function: require_once
With unique optical and chemical properties, carbon quantum dots (CQDs) find tremendous applications in chemistry, biology, and materials science to medicine. To expand the applicability of coal-derived CQDs from the liquid to solid state, we herein report the sustainable synthesis of solid phosphors from coal-derived CQDs using poly(vinyl alcohol) (PVA) and silica (SiO) as an organic and inorganic matrix. Two coal-derived CQDs were obtained using an eco-friendly ultrasonic-assisted wet oxidation method. The structural and chemical properties of the CQDs were extensively investigated and compared with commercial CQDs. The coal-derived CQDs exhibited blue fluorescence with 8.9 and 14.9% quantum yields. The CQDs were found to be self-co-doped with nitrogen and sulfur heteroatoms through surface and edge functional groups. Solid-state fluorescence of PVA/CQD composite films confirmed that the CQDs retained their excellent blue emission in a dry solid matrix. A facile one-pot sol-gel method was employed to fabricate SiO/CQD phosphors with the unique fluorescence emission. Due to their special structural features, coal-derived CQDs favored the heterogeneous nucleation and rapid formation of SiO/CQD phosphors. Further, coal-derived CQDs caused high-intensity white light emission with CIE coordinates of (0.312, 0.339) by endowing a suitable band gap structure in a SiO/CQD solid phosphor for potential optical applications.
Download full-text PDF |
Source |
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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC10357543 | PMC |
http://dx.doi.org/10.1021/acsomega.3c02884 | DOI Listing |
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