Bismuth molybdate (BMO) is a promising visible-driven photocatalyst and constructing heterojunctions in BMO-based materials is an effective way to enhance photocatalytic performance. In this study, boron-doped graphene quantum dots (BGQDs) were synthesized by one-step pyrolysis and carbonization, followed by the preparation of bismuth molybdate/boron-doped graphene quantum dots (BGQDs/BMO) heterojunction photocatalysts using in-situ growth method. The introduction of BGQDs significantly improved the photocatalytic nitrogen fixation activity under the irradiation of visible light and without scavengers. The highest NH yield was achieved with BGQDs/BMO-10, which was 3.48 times higher than pure phase BMO. This improvement was due to the formation of Z-scheme heterojunctions between BGQDs and BMO with the synergistic mechanism of interfacial charge transport and the generation of more protons. This study provides useful guidance for enhancing the visible-light nitrogen fixation performance of BMO materials.
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| http://dx.doi.org/10.1016/j.jcis.2023.07.085 | DOI Listing |
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