Versatile Protein and Its Subunit Biomolecules for Advanced Rechargeable Batteries.

Rechargeable batteries are of great significance for alleviating the growing energy crisis by providing efficient and sustainable energy storage solutions. However, the multiple issues associated with the diverse components in a battery system as well as the interphase problems greatly hinder their applications. Proteins and their subunits, peptides, and amino acids, are versatile biomolecules. Functional groups in different amino acids endow these biomolecules with unique properties including self-assembly, ion-conducting, antioxidation, great affinity to exterior species, etc. Besides, protein and its subunit materials can not only work in solid forms but also in liquid forms when dissolved in solutions, making them more versatile to realize materials engineering via diverse approaches. In this review, it is aimed to offer a comprehensive understanding of the properties of proteins and their subunits, and research progress of using these versatile biomolecules to address the engineering issues of various rechargeable batteries, including alkali-ion batteries, lithium-sulfur batteries, metal-air batteries, and flow batteries. The state-of-the-art advances in electrode, electrolyte, separator, binder, catalyst, interphase modification, as well as recycling of rechargeable batteries are involved, and the impacts of biomolecules on electrochemical properties are particularly emphasized. Finally, perspectives on this interesting field are also provided.