Light-Based 3D Printing of Complex-Shaped Photonic Colloidal Glasses.

Adv Mater

Complex Materials, Department of Materials, ETH Zurich, 8093, Zurich, Switzerland.

Published: November 2023

Colloidal glasses display angle-independent structural color that is tunable by the size and local arrangement of sub-micrometer particles. While films, droplets, and microcapsules with isotropic structural color have been demonstrated, the shaping of colloidal glasses in three dimensions remains an open manufacturing challenge. Here, a light-based printing platform for the shaping of colloidal glasses into 3D objects featuring complex geometries and vivid structural color after thermal treatment is reported. Rheology, photopolymerization, and calcination experiments are performed to design the photoreactive resins leading to printable colloidal glasses. With the help of microscopy, scattering, and optical characterization, it is shown that the photonic properties of the printed objects reflect the locally ordered microstructure of the glass. The capability of the platform in creating 3D objects with isotropic structural color is illustrated by printing lattices and miniaturized sculpture replicas with unique shapes and multimaterial designs.

Download full-text PDF

Source
http://dx.doi.org/10.1002/adma.202302868DOI Listing

Publication Analysis

Top Keywords

colloidal glasses
20
structural color
16
light-based printing
8
isotropic structural
8
shaping colloidal
8
colloidal
5
glasses
5
printing complex-shaped
4
complex-shaped photonic
4
photonic colloidal
4

Similar Publications

In this study, we demonstrate a novel and efficient fabrication methodology for nonclose-packed, two-dimensional (2D) colloidal crystals exhibiting square lattice structures. In our recent work, we detailed the formation of 2D colloidal crystals via the electrostatic adsorption of three-dimensional (3D) charged colloidal crystals onto oppositely charged substrates. These 3D colloidal crystals possessed a face-centered cubic (FCC) lattice structure with their (111) planes aligned parallel to the substrate, facilitating the formation of 2D crystals with triangular lattice arrangements upon adsorption.

View Article and Find Full Text PDF

Interfacial mechanisms of enhanced photoluminescence in AgI-doped red light emitting perovskite quantum dot glass.

J Colloid Interface Sci

January 2025

Institute of Optoelectronic Materials and Devices, College of Optical and Electronic Technology, China Jiliang University, Hangzhou 310018 PR China. Electronic address:

Red light emitting perovskite quantum dot (PQD) glass, with narrow-band emission and excellent stability, holds great potential for applications in liquid crystal displays. However, its low photoluminescence quantum yield (PLQY) remains the biggest obstacle limiting its practical application. Additionally, the mechanism behind the enhancement of the PLQY is not well understood, which restricts the further improvement of the PLQY in red light emitting PQD glass.

View Article and Find Full Text PDF

A wound, defined as a disruption in the continuity of the skin, is among the most common issues in the population and poses a significant burden on healthcare systems and economies worldwide. Despite the countless medical devices currently available to promote wound repair and skin regeneration, there is a growing demand for new skin devices that incorporate innovative biomaterials and advanced technologies. Bioglasses are biocompatible and bioactive materials capable of interacting with biological tissues.

View Article and Find Full Text PDF

Stabilizing bicontinuous particle-stabilized emulsions formed solvent transfer-induced phase separation.

Soft Matter

January 2025

Van 't Hoff Laboratory of Physical and Colloid Chemistry, Department of Chemistry, Debye Institute for Nanomaterials Science, Utrecht University, Utrecht, The Netherlands.

Bicontinuous particle-stabilized emulsions (bijels) are unique soft materials that combine the bulk properties of two immiscible fluids into a single interconnected structure. This structure is achieved through the formation of two interwoven fluid networks, stabilized by an interfacial layer of colloidal particles. Bijels with submicron-scale domain networks can be synthesized solvent transfer-induced phase separation (STrIPS).

View Article and Find Full Text PDF

Adhesive conductive wood-based hydrogel with high tensile strength as a flexible sensor.

Carbohydr Polym

March 2025

State Key Laboratory of Efficient Production of Forest Resources, Beijing 100083, China.

Conductive hydrogels have promising applications for flexible strain sensors. However, most hydrogels have poor tensile strength and are susceptible to damage, significantly impeding their potential for further application. Wood has been used to reinforce hydrogels, significantly enhancing their strength and dimensional stability.

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!