AI Article Synopsis
- Both types of complexes, pseudo-octahedral and pseudo-square pyramidal, show structural distortions, with the ruthenium atom not perfectly aligned along the expected symmetry axis.
- These distortions are significant because they promote or improve the π interactions between ruthenium and the iminoxolene π orbitals.
- The specific complexes mentioned are -(Diso)RuCl and -(Diso)Ru(PPh), which highlights the impact of geometric arrangement on their electronic interactions.
Article Abstract
Both pseudo-octahedral and pseudo-square pyramidal bis-iminoxolene complexes -(Diso)RuCl and -(Diso)Ru(PPh) are structurally distorted, with the ruthenium atom slipping off the twofold axis of the idealized coordination polyhedra. These distortions take place because they allow or enhance π interactions between ruthenium and the iminoxolene π orbitals.
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| http://dx.doi.org/10.1039/d3cc02943c | DOI Listing |
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