Photocatalytic Activity and Thermal Stability of Hybrid Metal-Polymer-Coordinated Complexes Derived from Gallic Acid and Ethylenediamine.

Three new hybrid metal-polymer-coordinated complexes (MPCs) of copper(II), cobalt(II), and nickel(II) ions with an organic polymer derived from gallic acid and ethylenediamine (GAEtH) were synthesized. The structures of GAEtH and MPCs were characterized with FT-IR, ultraviolet (UV)-Vis, H and C NMR spectroscopy, and elemental and thermogravimetric analysis. The results reveal that the organic polymer GAEtH exhibits an infinite one-dimensional chain structure, while the hybrid MPCs have a double chain structure, with the two chains joined by metal ions. The thermodynamic and kinetic parameters of the thermal degradation stages were determined by the Coats Redfern method, and the photocatalytic behaviors of the MPCs were investigated through the decomposition of methyl orange dye under UV irradiation.