Selective synthesis of boron-substituted enynes a one-pot diboration/protodeboration sequence.

Chem Commun (Camb)

Centre for Advanced Technology, Adam Mickiewicz University, Uniwersytetu Poznańskiego 10, 61-614 Poznan, Poland.

Published: August 2023

An efficient and facile one-pot protocol to access enynylboronates a Pt-catalyzed diboration/protodeboration strategy has been developed. The reaction is suitable for various silylsubstituted symmetrical and unsymmetrical 1,3-diynes, leading to π-conjugated organoboron compounds with excellent regio- and stereoselectivity.

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http://dx.doi.org/10.1039/d3cc02695gDOI Listing

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