A General Strategy for Developing Ultrasensitive "Transistor-Like" Thermochromic Fluorescent Materials for Multilevel Information Encryption.

Thermochromic fluorescent materials (TFMs) exhibit great potential in information encryption applications but are limited by low thermosensitivity, poor color tunability, and a wide temperature-responsive range. Herein, a novel strategy for constructing highly sensitive TFMs with tunable emission (450-650 nm) toward multilevel information encryption is proposed, which employs polarity-sensitive fluorophores with donor-acceptor-donor (D-A-D) type structures as emitters and long-chain alkanes as thermosensitive loading matrixes. The structure-function relationships between the performance of TFMs and the structures of both fluorescent emitters and phase-change molecules are systematically studied. Benefiting from the above design, the obtained TFMs exhibit over 9500-fold fluorescence enhancement toward the temperature change, as well as ultrahigh relative temperature sensitivity up to 80% K , which are first confirmed. Thanks to the superior transducing performance, the above-prepared TFMs can be further developed as information-storage platforms within a relatively narrow interval of temperature variation, including temperature-dominated multicolored information display and multilevel information encryption. This work will not only provide a novel perspective for designing superior TFMs for information encryption but also bring inspiration to the design and preparation of other response-switching-type fluorescent probes with ultrahigh conversion efficiency.