The reaction of the pyridine adduct of SO and tetra-n-butyl-ammonium cyanide, [N( Bu) ][CN] at room temperature leads to the unprecedented cyanido-sulfate anion [SO CN] stabilized in the salt [N( Bu) ][SO CN]. The anion is a pseudo-halogen congener of the well-known fluoro- and chloro-sulfates. The new anion has been studied by vibrational spectroscopy and theoretical calculations.
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| http://dx.doi.org/10.1002/chem.202301761 | DOI Listing |
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