Reconstruction of the acoustic relaxation absorption curve is a powerful approach to ultrasonic gas sensing, but it requires knowledge of a series of ultrasonic absorptions at various frequencies around the effective relaxation frequency. An ultrasonic transducer is the most widely deployed sensor for ultrasonic wave propagation measurement and works only at a fixed frequency or in a specific environment like water, so a large number of ultrasonic transducers operating at various frequencies are required to recover an acoustic absorption curve with a relative large bandwidth, which cannot suit large-scale practical applications. This paper proposes a wideband ultrasonic sensor using a distributed Bragg reflector (DBR) fiber laser for gas concentration detection through acoustic relaxation absorption curve reconstruction. With a relative wide and flat frequency response, the DBR fiber laser sensor measures and restores a full acoustic relaxation absorption spectrum of CO using a decompression gas chamber between 0.1 and 1 atm to accommodate the main molecular relaxation processes, and interrogates with a non-equilibrium Mach-Zehnder interferometer (NE-MZI) to gain a sound pressure sensitivity of -45.4 dB. The measurement error of the acoustic relaxation absorption spectrum is less than 1.32%.
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http://dx.doi.org/10.3390/s23104740 | DOI Listing |
Nat Commun
January 2025
Inorganic Chemistry Laboratory, University of Oxford, South Parks Road, Oxford, OX1 3QR, United Kingdom.
Inorganic semiconductors based on heavy pnictogen cations (Sb and Bi) have gained significant attention as potential nontoxic and stable alternatives to lead-halide perovskites for solar cell applications. A limitation of these novel materials, which is being increasingly commonly found, is carrier localization, which substantially reduces mobilities and diffusion lengths. Herein, CuSbSe is investigated and discovered to have delocalized free carriers, as shown through optical pump terahertz probe spectroscopy and temperature-dependent mobility measurements.
View Article and Find Full Text PDFNat Commun
December 2024
Department of Chemistry, School of Science and Research Center for Industries of the Future, Westlake University, Hangzhou, Zhejiang Province, China.
The solid-state integration of molecular electron spin qubits could promote the advancement of molecular quantum information science. With highly ordered structures and rational designability, microporous framework materials offer ideal matrices to host qubits. They exhibit tunable phonon dispersion relations and spin distributions, enabling optimization of essential qubit properties including the spin-lattice relaxation time (T) and decoherence time.
View Article and Find Full Text PDFJ Chem Phys
December 2024
Laboratório de Espectroscopia Molecular, Departamento de Química Fundamental, Instituto de Química, Universidade de São Paulo, 05513-970 São Paulo, SP, Brazil.
Molecular dynamics (MD) simulation is used to study the intermolecular dynamics in the THz frequency range of the ionic liquid 1-ethyl-3-methylimidazolium bis(fluorosulfonyl)imide, [C2C1im][FSI]. Non-polarizable and polarizable models for classical MD simulation are compared using as quality criteria ab initio molecular dynamics (AIMD) and experimental data from far-infrared (FIR) spectroscopy and previously published data of inelastic x-ray scattering (IXS). According to data from IXS spectroscopy, incorporating polarization in the classical MD simulation has relatively little effect on the dispersion curve (excitation frequency vs wavevector) for longitudinal acoustic modes.
View Article and Find Full Text PDFACS Appl Mater Interfaces
December 2024
Instituto de Investigaciones en Ciencia y Tecnología de Materiales (INTEMA), CONICET/UNMdP, Av. Colón 10850, B7606BWV, Mar del Plata, Argentina.
This study addresses the extension of the service life of carbon-fiber reinforced epoxies by inducing thermal healing of microcracks through the use of a vitrimer as a polymeric matrix. Our aim was to explore the feasibility of using a blend of selected carboxylic acids (citric, glutaric, and sebacic acids) and commercial monomers to design a matrix specifically developed for technological implementation in composites with the ability of intrinsic repair of microcracks under moderate (even remote) heating treatments. The selection of the formulation (the acid blend, catalysts, and monomers) was the result of an exhaustive prescreening analysis of processing requisites and final properties.
View Article and Find Full Text PDFUltrasonics
December 2024
Department of Information Engineering and Computer Science, University of Trento, Italy.
Background: Shear wave elastography (SWE) is a technique that quantifies tissue stiffness by assessing the speed of shear waves propagating after being excited by acoustic radiation force. SWE allows the quantification of elastic tissue properties and serves as an adjunct to conventional ultrasound techniques, aiding in tissue characterization. To capture this transient propagation of the shear wave, the ultrasound device must be able to reach very high frame rates.
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