New insight into thermal hydrolysis of sewage sludge from solubilisation analysis.

Thermal hydrolysis, a sludge pre-treatment process prior to anaerobic digestion, is increasing in popularity in academia and industry due to the potential of biogas production enhancement. However, there is a limited understanding of the solubilisation mechanism, which significantly influences the biogas yield. This study evaluated the influence of flashing, reaction time, and temperature to understand the mechanism. It was found that while hydrolysis is the primary process (responsible for approximately 76-87% of sludge solubilisation), the sudden decompression via flashing at the end of the process, creating shear force to break the cell membrane, contributes a considerable percentage (approximately 24-13% depended on the treatment conditions) to the solubilisation of treated sludge. More importantly, the decompression helps significantly shorten the reaction time from 30 min to 10 min, which in turn reduces the sludge's colour, minimises energy consumption, and eliminates the formation of inhibitory compounds for anaerobic digestion. However, a considerable loss in volatile fatty acids (650 mg L⁻ of acetic acid at 160 °C) during flash decompression should be considered.