Switchable materials have attracted enormous interest due to their promising applications in important fields such as sensing, electronic components, and information storage. Nevertheless, obtaining multifunctional switching materials is still a problem worth investigating. Herein, by incorporating (-, -, -2-amino-1-propanol) as the templating cation, we have obtained (-, -, -HTMPA)CdCl (HTMPA = 1-hydroxy-, , -trimethyl-2-propanaminium). We have adopted a chiral chemistry strategy that causes (-HTMPA)CdCl in the central symmetric space to crystallize in the chiral space group. Based on the modulation of the homochiral strategy, (, HTMPA)CdCl shows a dual phasic transition at 269 and 326 K and a switchable second-harmonic generation response. In addition, (-, -HTMPA)CdCl is chiral switchable material to exhibit stable dual dielectric and second-harmonic generation (SHG) switches. This work provides an approach to exploring multifunctional chiral switchable materials.
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| http://dx.doi.org/10.1021/acs.inorgchem.3c01640 | DOI Listing |
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