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Entropy stabilized cubic LiLaZrO with reduced lithium diffusion activation energy: studied using solid-state NMR spectroscopy. | LitMetric
Stabilizing cubic polymorph of LiLaZrO at low temperatures is challenging and currently limited to mono- or dual-ion doping with aliovalent ions. Herein, a high-entropy strategy at the Zr sites was deployed to stabilize the cubic phase and lower the lithium diffusion activation energy, evident from the static Li and MAS Li NMR spectra.
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