The innovative adsorbents known as the Metal-organic Framework (MOFs) had a high specific surface area, various structural types, and good chemical stability. MOFs have been produced through hydrothermal, mechanochemical, microwave-assisted, gelation, and other synthesis methods, and the solvothermal process is one of them that researchers frequently utilize. The UiO materials have a more comprehensive application potential than different subtypes of MOFs among the numerous MOFs that have been synthesized. The synthesis of MOFs and their composites, as well as the adsorption characteristics of UiO materials in the adsorption of various heavy metal ions, have all been examined and summarized in this study.
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http://dx.doi.org/10.3389/fchem.2023.1211989 | DOI Listing |
Chemosphere
December 2024
College of Land Science and Technology, China Agricultural University, Beijing 100193, PR China. Electronic address:
Heavy metals released from metallic sulfidic tailings pose significant environmental threats by contaminating surface and groundwater in mining areas. Sustainable rehabilitation methods are essential to remove or stabilize these metals, improving the quality of acid mine drainage and minimizing pollution. This study examines the adsorption capacity of zinc ions (Zn) by different iron-silicate mineral groups under natural weathering and bacteria-regulated weathered conditions.
View Article and Find Full Text PDFInt J Biol Macromol
December 2024
Department of Chemistry, Imam Khomeini International University, P.O. Box 288, Qazvin, Iran.
A novel nanocomposite magnetic hydrogel was synthesized based on κ-carrageenan, acrylic acid, and activated carbon as an absorbent for removing heavy metal ions from aqueous solution. FT-IR spectroscopy, thermogravimetric analysis (TGA), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and vibration sample magnetometer (VSM) were employed to confirm the structure of the nanocomposite hydrogels. The effects of contact time, pH, particle size, temperature, and metal ion concentration on the metal ion adsorption were investigated.
View Article and Find Full Text PDFSci Rep
December 2024
Faculty of Chemical Engineering, Urmia University of Technology, Urmia, 17165‑57166, Iran.
In this research, 3-(trimethoxysilyl)propyl methacrylate (MPS) silane agent was applied to modify the extracted wheat straw (WS) cellulose as a natural biopolymer. Polyacrylonitrile (PAN) was attached to the MPS-modified WS (MPS-WS) via in-situ polymerization to form PAN-WS biocomposite. AO-WS amidoximated biocomposite adsorbent was synthesized through amidoxime reaction and the effects of different parameters including agitation speed, metal ion concentration, and adsorbent dosage on its efficiency of Pb(II) removal were investigated using the Taguchi experimental design method.
View Article and Find Full Text PDFCrown ether is widely used in water purification because of its ring structure and good selective adsorption of specific heavy metals. However, its high cost and difficulty in recycling limit the purification of heavy metals in water. The anisotropic [2,4]-dibenzo-18-crown-6-modified bamboo pulp aerogel (DB18C6/PA) is successfully synthesized by microwave irradiation and directional freezing technology.
View Article and Find Full Text PDFBMC Chem
December 2024
School of Chemical and Environmental Engineering, International University, Quarter 6, Linh Trung Ward, Thu Duc City, Ho Chi Minh City, Vietnam.
Magnetic activated carbon has been proved its separation ability to overcome a main drawback of activated carbon powder. However, effect of magnetization method on characterizations and Chromium (VI) adsorption of this adsorbent from Artocarpus Heterophyllus Peel (jackfruit peel) has not been investigated yet. This study magnetized jackfruit peel activated carbon using thermochemical and co-precipitation methods.
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