Due to the severe toxicity of triethylamine (TEA), the preparation of chemsensors with high sensitivity, low cost and visualization for TEA detection has been a research hotspot. However, based on the fluorescence turn-on detection of TEA remains rare. In this work, three two-dimensional conjugated polymers (2D CPs) were prepared by chemical oxidation polymerization. These sensors show a quick response and excellent selectivity toward TEA at room temperature. The minimum limit of detection (LOD) for TEA was 3.6 nM in the range of 10 μM ∼ 30 μM. Interestingly, the paper sensor based on P2-HCl can quantitatively detect TEA gas within 20 s, which showed great application potential in fields of environmental monitoring. Besides, Fourier transform infrared spectra (FT-IR), scanning electron microscope (SEM) and X-ray photoelectron spectroscopy (XPS) data were used to thoroughly interpret the sensing mechanism. This work provided an effective method for the development of 2D fluorescent chemosensors for TEA detection.
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| http://dx.doi.org/10.1016/j.talanta.2023.124868 | DOI Listing |
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