The development of narrow-band thermal emitters operating at mid-infrared (MIR) wavelengths is vital in numerous research fields. However, the previously reported results obtained with metallic metamaterials were not successful in achieving narrow bandwidths in the MIR region, which suggests low temporal coherence of the obtained thermal emissions. In this work, we demonstrate a new design strategy to realize this target by employing the bound state in the continuum (BIC) modes of the Fabry-Perot (FP) type. When a disk array of high-index dielectric supporting Mie resonances is separated from a highly reflective substrate by a low refractive index spacer layer with appropriate thickness, the destructive interference between the disk array and its mirror with respect to the substrate leads to the formation of FP-type BIC. Quasi-BIC resonances with ultra-high Q-factor (>10) are achievable by engineering the thickness of the buffer layer. This strategy is exemplified by an efficient thermal emitter operating at a wavelength of 4.587 µm with the on-resonance emissivity of near-unity and the full-width at half-maximum (FWHM) less than 5 nm even along with consideration of metal substrate dissipation. The new thermal radiation source proposed in this work offers ultra-narrow bandwidth and high temporal coherence along with the economic advantages required for practical applications, compared to those infrared sources made from III-V semiconductors.
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ACS Nano
January 2025
Institute of Functional Nano & Soft Materials (FUNSOM), Joint International Research Laboratory of Carbon-Based Functional Materials and Devices, Soochow University, Suzhou 215123, Jiangsu, China.
Thermally activated delayed fluorescence (TADF) materials have received increasing attention from organic electronics to other related fields, such as bioapplications and photocatalysts. However, it remains a challenging task for TADF emitters to showcase the versatility concurrent with high performance in multiple applications. Herein, we first present such a proof-of-concept TADF material, namely, QCN-SAC, through strategically manipulating exciton dynamics.
View Article and Find Full Text PDFJ Phys Chem A
January 2025
Shandong Province Key Laboratory of Medical Physics and Image Processing Technology, School of Physics and Electronics, Shandong Normal University, Jinan 250014, China.
The strategy of designing efficient room-temperature phosphorescence (RTP) emitters based on hydrogen bond interactions has attracted great attention in recent years. However, the regulation mechanism of the hydrogen bond on the RTP property remains unclear, and corresponding theoretical investigations are highly desired. Herein, the structure-property relationship and the internal mechanism of the hydrogen bond effect in regulating the RTP property are studied through the combination of quantum mechanics and molecular mechanics methods (QM/MM) coupled with the thermal vibration correlation function method.
View Article and Find Full Text PDFAdv Mater
January 2025
Organic Semiconductor Centre, EaStCHEM School of Chemistry, University of St Andrews, St Andrews, Fife, KY16 9ST, UK.
The development of narrowband emissive, bright, and stable solution-processed organic light-emitting diodes (SP-OLEDs) remains a challenge. Here, a strategy is presented that merges within a single emitter a TADF sensitizer responsible for exciton harvesting and an MR-TADF motif that provides bright and narrowband emission. This emitter design also shows strong resistance to aggregate formation and aggregation-cause quenching.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
January 2025
South China University of Technology School of Materials Science and Engineering, State Key Laboratory of Luminescent Materials and Devices and Institute of Polymer Optoelectronic Materials and Devices, 381 Wushan Road, 510640, Guangzhou, CHINA.
Chalcogen-containing carbonyls, specifically thioxanthone (TX), hold great potential in organic light-emitting diodes (OLEDs). While the development of narrowband OLEDs with chalcogen-containing carbonyls remains challenging due to difficulties in achieving both high device efficiency and narrow emission spectra. Herein, via a strategic incorporation of the TX moiety, two orange-red narrowband emitters, 2TXBN and BNTXBN, are designed and synthesized for the first time.
View Article and Find Full Text PDFSmall
January 2025
School of Mechanical Engineering, Korea University, 145 Anam-Ro, Seongbuk-Gu, Seoul, 02841, Republic of Korea.
Passive temperature controls like passive daytime radiative cooling (PDRC)-heating (PDRH), and thermal insulation are essential to meet the growing demand for energy-efficient thermal solutions. When combined with advanced functions like electromagnetic interference shielding, these technologies can significantly enhance scalability. However, existing approaches using single thin films or uniform porous materials face inherent limitations in optimizing versatile functions, while lightweight, insulating aerogels can extend their multifunctionality by manipulating pores and fillers.
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