New valproate Ir(III) and Rh(III) half-sandwich conjugates containing a C,N-phenylbenzimidazole chelated ligand have been synthesized and characterized. The valproic acid conjugation to organometallic fragments seems to switch on the antibacterial activity of the complexes towards and Gram-positive bacteria.

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http://dx.doi.org/10.1039/d3dt01678aDOI Listing

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