J Phys Chem C Nanomater Interfaces
Department of Chemistry and NIS Centre of Excellence, University of Turin, via Giuria 9, 10125 Torino, Italy.
Published: June 2023
Engineering two cooperative sites into a catalyst implies the onset of synergistic effects related to the existence of short-range electronic interactions between two metal components. However, these interactions and the relative structure-property correlations are often difficult to obtain. Here we show that hyperfine spectroscopy has the potential to reveal the presence of V-O-Mo linkages assessing the degree of spin density transfer from paramagnetic V species to proximal oxo-bridged Mo metal ions. The dimer species were prepared by adsorption of Mo(CO) in the pores of SAPO-5, followed by thermal decomposition and oxidation and subsequent grafting of anhydrous VCl(g) followed by hydrolysis and dehydration. The metal species react with SAPO protons during the exchange process and generate new Lewis acid sites, which act as redox centers. X- and Q-band EPR and HYSCORE experiments have been employed to monitor the local environment of V species obtaining direct evidence for spin delocalization over Al, P, Mo, and Mo nuclei, demonstrating the presence of bimetallic V-O-Mo well-defined structures.
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http://dx.doi.org/10.1021/acs.jpcc.3c01817 | DOI Listing |
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Department of Physics, Chemistry and Pharmacy, University of Southern Denmark, Campusvej 55, DK-5230 Odense M, Denmark.
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