Understanding the Bifunctional Trends of Fe-Based Binary Single-Atom Catalysts.

Binary single-atom catalysts (BSACs) have demonstrated fascinating activities compared to single atom catalysts (SACs) for oxygen reduction reaction (ORR) and oxygen evolution reaction (OER). Notably, Fe SACs is one of the most promising ORR electrocatalysts, and further revealing the synergistic effects between Fe and other 3d transition metals (M) for FeM BSACs are very important to enhance bifunctional performance. Herein, density functional theory (DFT) calculations are first adapted to demonstrate the role of various transition metals on the bifunctional activity of Fe sites, and a notable volcano relationship is established through the generally accepted adsorption free energy that ΔG for ORR, and ΔG -ΔG for OER, respectively. Further, ten of the atomically dispersed FeM anchored on nitrogen-carbon support (FeM-NC) are successfully synthesized with typical atomic dispersion by a facile movable type printing method. The experimental data confirms the bifunctional activity diversity of FeM-NC between the early- and late- transition metals, agrees very well with the DFT results. More importantly, the optimal FeCu-NC shows the expected performance with high ORR and OER activity, thereby, the assembled rechargeable zinc-air battery delivers a high power density of 231 mW cm , and an impressive stability that can be stably operated over 300 h.