Identification of possible sources for potentially toxic elements and polycyclic aromatic hydrocarbons and their spatially varying relationships in urban soils of Dublin, Ireland.

Potentially toxic elements (PTEs) and polycyclic aromatic hydrocarbons (PAHs) harm the ecosystem and human health, especially in urban areas. Identifying and understanding their potential sources and underlying interactions in urban soils are critical for informed management and risk assessment. This study investigated the potential sources and the spatially varying relationships between 9 PTEs and PAHs in the topsoil of Dublin by combining positive matrix factorisation (PMF) and geographically weighted regression (GWR). The PMF model allocated four possible sources based on species concentrations and uncertainties. The factor profiles indicated the associations with high-temperature combustion (PAHs), natural lithologic factors (As, Cd, Co, Cr, Ni), mineralisation and mining (Zn), as well as anthropogenic inputs (Cu, Hg, Pb), respectively. In addition, selected representative elements Cr, Zn, and Pb showed distinct spatial interactions with PAHs in the GWR model. Negative relationships between PAHs and Cr were observed in all samples, suggesting the control of Cr concentrations by natural factors. Negative relationships between PAHs and Zn in the eastern and north-eastern regions were related to mineralisation and anthropogenic Zn-Pb mining. In contrast, the surrounding regions exhibited a natural relationship between these two variables with positive coefficients. Increasing positive coefficients from west to east were observed between PAHs and Pb in the study area. This special pattern was consistent with prevailing south-westerly wind direction in Dublin, highlighting the predominant influences on PAHs and Pb concentrations from vehicle and coal combustion through atmospheric deposition. Our results provided a better understanding of geochemical features for PTEs and PAHs in the topsoil of Dublin, demonstrating the efficiency of combined approaches of receptor models and spatial analysis in environmental studies.