NASICON-type NaNbV(PO) electrode material synthesized by the Pechini sol-gel technique undergoes a reversible three-electron reaction in a Na-ion cell which corresponds to the Nb/Nb, Nb/Nb, and V/V redox processes and provides a reversible capacity of 180 mAh·g. The sodium insertion/extraction takes place in a narrow potential range at an average potential of 1.55 V versus Na/Na. Structural characterization by and X-ray diffraction disclosed the reversible evolution of the NaNbV(PO) polyhedron framework during cycling, while XANES measurements in the regime confirmed the multielectron transfer upon sodium intercalation/extraction into NaNbV(PO). This electrode material demonstrates extended cycling stability and excellent rate capability maintaining the capacity value of 144 mAh·g at 10 C current rates. It can be regarded as a superior anode material suitable for application in high-power and long-life sodium-ion batteries.
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