Synchronization and alignment of model oscillators based on Quincke rotation.

Colloidal spheres in weakly conductive fluids roll back and forth across the surface of a plane electrode when subject to strong electric fields. The so-called Quincke oscillators provide a basis for active matter based on self-oscillating units that can move, align, and synchronize within dynamic particle assemblies. Here, we develop a dynamical model for oscillations of a spherical particle and investigate the coupled dynamics of two such oscillators in the plane normal to the field. Building on existing descriptions of Quincke rotation, the model describes the dynamics of the charge, dipole, and quadrupole moments due to charge accumulation at the particle-fluid interface and particle rotation in the external field. The dynamics of the charge moments are coupled by the addition of a conductivity gradient, which describes asymmetries in the rates of charging near the electrode. We study the behavior of this model as a function of the field strength and gradient magnitude to identify the conditions required for sustained oscillations. We investigate the dynamics of two neighboring oscillators coupled by far field electric and hydrodynamic interactions in an unbounded fluid. Particles prefer to align and synchronize their rotary oscillations along the line of centers. The numerical results are reproduced and explained by accurate low-order approximations of the system dynamics based on weakly coupled oscillator theory. The coarse-grained dynamics of the oscillator phase and angle can be used to investigate collective behaviors within ensembles of many self-oscillating colloids.