Relation disentanglement, the potential risk assessment, and source identification of heavy metals in the sediment of the Changzhao Reservoir, Zhejiang Province.

Heavy metal contamination in the water body is a distinctly important issue for the water security of the reservoir. 114 sediment samples of Changzhao Reservoir were collected to investigate the spatial (horizontal and vertical) distribution characteristics, risk assessment, and source identification of heavy metals. The concentrations of heavy metals at the surface layer of sediment were slightly higher compared with that at the middle and bottom layer sediment in the most sampling sites. The concentration of Zn and Cd was significantly different in the different depths of sediment (P ≤ 0.01, Tukey HSD test). pH and Cd were identified as the key factors for TOC in the sediment by the Boruta algorithm. The proportion of "uncontaminated to moderately contaminated" for Cd, Zn, and As in the surface layer was 84.21%, 47.37%, and 34.21%, which indicated that the quality of sediment was mostly impacted by Cd, Zn, and As. The agricultural non-point source pollution is dominant according to the source identification method of APCS-MLR. Overall, this paper presents the distribution and conversion trends of heavy metals and provides the insights of the reservoir protection in the future work.