Lignin-derived sulfonate base metal-free N, S co-doped carbon microspheres doped with different nitrogen sources as catalysts for oxygen reduction reactions.

The oxygen reduction reaction (ORR) is an important step in the widespread application of metal-air batteries, so it is necessary to study and develop low-cost and efficient metal-free carbon-based catalysts to catalyze the ORR reaction. Heteroatomic doping, especially N and S co-doped carbon materials, has received much focus as a promising ORR catalyst. Meanwhile, the lignin material has high carbon content, wide source, and low price, and has wide application prospects for the preparation of carbon material catalysts. Here we report a hydrothermal‑carbonation preparation method for the synthesis of carbon microspheres by utilizing lignin derivatives as carbon precursors. And a variety of N, S co-doped carbon microsphere materials were prepared by adding different nitrogen sources (urea, melamine, NHCl) to the microspheres. The N, S co-doped carbon microspheres (NSCMS-MLSN) catalysts achieved with NHCl as the nitrogen source displayed superior RR catalytic activity with high half-wave potential (E = 0.83 V vs. RHE) and current density (J = 4.78 mA cm). This work provides some references on the method of preparing carbon materials co-doped with N and S and the choice of nitrogen sources.