AI Article Synopsis
- Lanthanide ions are gaining interest due to their unique optical and magnetic properties, particularly in the study of single-molecule magnets (SMM) and chiral complexes with circularly polarized luminescence (CPL).
- The integration of SMM and CPL in a single molecule is rare, making it an exciting area for multifunctional material design.
- Researchers synthesized and characterized four chiral coordination compounds with Yb(iii) ions, which exhibited both field-induced SMM properties and near-infrared CPL in solid form.
Article Abstract
Lanthanide ions have attracted great interest owing to their optical and magnetic properties. Single-molecule magnet (SMM) behavior has been a fascinating science for thirty years. Moreover, chiral lanthanide complexes allow the observation of remarkable circularly polarized luminescence (CPL). However, the combination of both SMM and CPL behaviors in a single molecular system is very rare and deserves attention in the design of multifunctional materials. Four chiral one-dimensional coordination compounds involving 1,1'-Bi-2-naphtol (BINOL)-derived bisphosphate ligands and the Yb(iii) centre were synthesized and characterized by powder and single-crystal X-ray diffraction. All the Yb(iii)-based polymers displayed field-induced SMM behavior with magnetic relaxation occurring by applying Raman processes and near infrared CPL in the solid state.
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|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC10249065 | PMC |
| http://dx.doi.org/10.1039/d3tc00858d | DOI Listing |
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