A major challenge in the biodiesel industry is the availability of high-quality vegetable oil feedstocks. Thus, there is a continuous search for quality biodiesel feedstock whose production will trigger economic impact on the agricultural sector, minimize land degradation and without significant disruption to the food chain. In this work, we extracted and analysed oil from neglected and underutilized Cucumeropsis mannii seeds for their potential in biodiesel production. The oil content of seed was 40.8 ± 0.56%. GC-MS analysis of the oil revealed the presence of 47.0% saturated fatty (predominantly palmitic acid, stearic acid) and 53.0% of unsaturated fatty acids (predominantly oleic, linoleic and erucic acids). The physicochemical properties were determined and values were as follows: iodine value (111.07 ± 0.15 g/100 g), saponification value (192.03 ± 0.37 mg/kg of oil), peroxide value (2.60 ± 0.10 meq/kg), acid value (4.20 ± 0.02 mgKOH/g) free fatty acid (2.51 ± 0.02%), relative density (0.93 ± 0.02), the refractive index at 28 °C (1.46 ± 0.04) and viscosity at 30 °C (3.00 ± 0.10 mm/s). The fuel properties namely, cloud point, pour point, flash point and caloric value were determined and the values were 3.03 ± 0.11 °C, 1.00 ± 0.10 °C, 279.04 ± 0.99 °C and 31.10 ± 0.11 MJ/kg, respectively. In addition, the protein content of the defatted seed was found to be 47.4 ± 0.61 g/100 g. The defatted protein-rich cakes can be upgraded as a food additive; thus the seed oil can serve as biodiesel feedstock without altering the food chain. These characteristics demonstrate the potential of oil as a high-quality feedstock for biodiesel production. We envisage that its utilization as biodiesel feedstock will improve the market value of these seeds, thus supporting the economic development of local farmers in rural areas.
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http://dx.doi.org/10.1016/j.heliyon.2023.e16799 | DOI Listing |
Environ Sci Pollut Res Int
January 2025
Biofuel Laboratory, Department of Energy, Tezpur University, Assam, 784028, India.
Agro-processing industries generate a substantial quantity of biomass wastes. Conversion of these wastes into valuable material could be profitable considering both environmental and economic aspects. Among various biomass conversion methods, hydrothermal conversion can be used for co-production of biofuel and other valuable materials like carbon quantum dots (CQDs) and activated carbons.
View Article and Find Full Text PDFSci Rep
January 2025
Department of Chemistry, Faculty of Science, Universiti Teknologi Malaysia, 81310, Skudai, Johor Bharu, Malaysia.
As the demand for sustainable energy sources intensifies, biodiesel emerges as a compelling renewable alternative to petroleum-based fuels. Leveraging waste cooking oil (WCO) as a feedstock not only offers an environmentally friendly fuel source but also addresses waste disposal issues. However, biodiesel production from WCO faces challenges, particularly due to its high free fatty acid (FFA) content, which can hinder efficient conversion and lead to soap formation in traditional alkaline-catalysed processes.
View Article and Find Full Text PDFSci Total Environ
December 2024
Department of Chemical Engineering, Federal University of Santa Maria, 1000, Roraima Avenue, Santa Maria, RS 97105-900, Brazil. Electronic address:
Lignocellulosic waste, like corn stover (CS), is widely produced and serves as a key feedstock for biofuels and biochemicals. Semi-continuous subcritical water hydrolysis (SWH) is an eco-friendly method that breaks down cellulose and hemicellulose bonds. To boost fermentable sugar (FS) yields, steam explosion (SE) pretreatment was tested on CS, achieving a cellulose content of 74.
View Article and Find Full Text PDFJ Hazard Mater
December 2024
Civil & Environmental Engineering, University of Nebraska Lincoln, Lincoln, NE 68588, USA.
Little is known about the potential impact of point source contamination from seed treatment pesticide residues and degradation products in waste products in treated seed. The presence of these pesticides and their degradation products in the environment has been associated with toxic effects on non-target organisms including bees, aquatic organisms and humans. In this study, we investigated the occurrence of twenty-two pesticide residues and their degradation products in two streams receiving runoff from land-applied wet cake, applied and spilled wastewater originating at a biofuels production facility using pesticide-treated seed as a feedstock.
View Article and Find Full Text PDFChembiochem
December 2024
University of Lille, UMRtBioEcoAgro, PolytechLille Bd Langevin, 59655, Villeneuve d'Ascq, FRANCE.
The process to synthesize biodiesel is well-developed and optimized to overcome the disadvantages like the competition with agriculture using feedstock, and the problematics in the process. Oils from waste and enzymatic catalysis have proven to be good solutions to these problems. Lipases are currently the most commonly used enzymes in the transesterification of oils; nevertheless, enzymes have a high cost and must be immobilized to offer repetitive reuse.
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