The widespread use of polymers in the high-performance engineering applications brings challenges in the field of liquid lubrication in order to separate the rubbing surfaces by the coherent fluid-film thickness relative to not only the inelastic material response of the polymers. The determination of the mechanical properties by the nanoindentation and the dynamic mechanical analysis represents the key methodology to identify the viscoelastic behavior with respect to the intense frequency and temperature dependance exhibited by polymers. The fluid-film thickness was examined by the optical chromatic interferometry on the rotational tribometer in the ball-on-disc configuration. Based on the experiments performed, first, the complex modulus and the damping factor for the PMMA polymer describing the frequency and temperature dependence were obtained. Afterwards, the central as well as minimum fluid-film thickness were investigated. The results revealed the operation of the compliant circular contact in the transition region very close to the boundary between the Piezoviscous-elastic and Isoviscous-elastic modes of the elastohydrodynamic lubrication regime, and a significant deviation of the fluid-film thickness from the prediction models for both modes in dependence on the inlet temperature.
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http://dx.doi.org/10.3390/polym15112528 | DOI Listing |
Science
April 2024
Laboratoire Colloïdes et Matériaux Divisés, CBI, ESPCI Paris, Université PSL, CNRS, 75005 Paris, France.
Oil and water can only be mixed by dispersing droplets of one fluid in the other. When two droplets approach one another, the thin film that separates them invariably becomes unstable, causing the droplets to coalesce. The only known way to avoid this instability is through addition of a third component, typically a surfactant, which stabilizes the thin film at its equilibrium thickness.
View Article and Find Full Text PDFLangmuir
April 2024
Norwegian Tribology Center, Department of Mechanical and Industrial Engineering, Norwegian University of Science and Technology (NTNU), Trondheim, 7491, Norway.
Carboxylic acids make up a well-known group of organic friction modifiers (OFMs). OFMs can present different types of polar heads that can eventually lead to different surface adsorption properties and tribological responses. Therefore, the goal of this work is to study the effects of the polar head type on the frictional and wear performances of carboxylic acids in a water-based lubricant.
View Article and Find Full Text PDFRev Sci Instrum
June 2023
Laboratoire de Tribologie et Dynamique des Systèmes, CNRS UMR 5513, École Centrale de Lyon, 36 avenue Guy de Collongue, 69134 Ecully Cedex, France.
A model hydrodynamic lubrication tribometer consisting of two hydrodynamic journal bearings working under thin film conditions was developed to investigate the mechanisms of hydrodynamic friction with low-viscosity fluids and the role of surface effects. A small nominal radial clearance of about 5 µm was considered between the two surfaces. This fully instrumented setup provides in situ information on the sheared fluid film in terms of simultaneous measurements of film thickness; localization and extension of the cavitation zone, with a resolution of 30°; nominal friction torques up to 0.
View Article and Find Full Text PDFJ Chem Phys
October 2023
Chemical and Biomolecular Engineering Department, University of California, Berkeley, California 94720, USA.
We report on viscous adhesion measurements conducted in sphere-plane geometry between a rigid sphere and soft surfaces submerged in silicone oils. Increasing the surface compliance leads to a decrease in the adhesive strength due to elastohydrodynamic deformation of the soft surface during debonding. The force-displacement and fluid film thickness-time data are compared to an elastohydrodynamic model that incorporates the force measuring spring and finds good agreement between the model and data.
View Article and Find Full Text PDFACS Appl Polym Mater
September 2023
Functional Polymer Surfaces Department of Molecules & Materials MESA+ Institute for Nanotechnology, University of Twente, P.O. Box 217, 7500 AE Enschede, The Netherlands.
We present a facile procedure for preparing thick (up to 300 nm) poly(3-sulfopropyl methacrylate) brushes using SI-ARGET-ATRP by conducting the reaction in a fluid film between the substrate and a coverslip. This method is advantageous in a number of ways: it does not require deoxygenation of the reaction solution, and the monomer conversion is much higher than usual since only a minimal amount of solution (microliters) is used, resulting in a tremendous reduction (∼50×) of wasted reagents. Moreover, this method is particularly suitable for grafting brushes to large substrates.
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