The title compound, having the mol-ecular formula [RuI(η-CH)(CHN)]PF, crystallizes in the triclinic ( = 2) space group as a half-sandwich complex resembling a three-legged piano stool. Important geometrical parameters include Ru-cymene centroid = 1.6902 (17) Å, Ru-I = 2.6958 (5) Å, [Ru-N] = 2.072 (3) Å, N1-Ru-N2 = 76.86 (12)° and a dihedral angle between the planes of the two rings of the bipyridyl system of 5.9 (2)°. The PF ion was treated with a twofold disorder model, refining to a 65.0 (8):35.0 (8) occupancy ratio. The crystal packing features C-H⋯F/I inter-actions.
Download full-text PDF |
Source |
|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC10242728 | PMC |
| http://dx.doi.org/10.1107/S2414314623003929 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
The title compound, [Ir(CHN)(CHN)]PF·CHOH, crystallizes in the 2/ space group with one monocationic iridium complex, one hexa-fluorido-phosphate anion, and one methanol solvent mol-ecule of crystallization in the asymmetric unit, all in general positions. The anion and solvent are linked to the iridium complex cation hydrogen bonding. All bond lengths and angles fall into expected ranges compared to similar compounds.
View Article and Find Full Text PDFΔ-Bis[()-2-(4-isopropyl-4,5-di-hydro-oxazol-2-yl)phenolato-κ , ](1,10-phenanthroline-κ ,')ruthenium(III) hexa-fluorido-phosphate.
IUCrdata
September 2024
Department of Chemical Sciences, University of Johannesburg, Auckland Park, 2006, Johannesburg, South Africa.
The title compound, [Ru(CHNO)(CHN)]PF crystallizes in the tetra-gonal Sohnke space group 422. The two bidentate chiral salicyloxazoline ligands and the phenanthroline co-ligand coordinate to the central Ru atom through N,O and N,N atom pairs to form bite angles of 89.76 (15) and 79.
View Article and Find Full Text PDFBis[2,6-bis-(1-benzimidazol-2-yl)pyridine]ruthenium(II) bis(hexa-fluorido-phosphate) diethyl ether tris-olvate.
IUCrdata
March 2024
Department of Chemistry, St. Francis Xavier University, Antigonish, Nova Scotia, Canada, B2G 2W5.
The title compound, [Ru(CHN)](PF)·3CHO, was obtained from the reaction of Ru(bimpy)Cl [bimpy is 2,6-bis-(1-benzimidazol-2-yl)pyridine] and bimpy in refluxing ethanol followed by recrystallization from diethyl ether/aceto-nitrile. At 125 K the complex has ortho-rhom-bic (2) symmetry. It is remarkable that the structure is almost centrosymmetric.
View Article and Find Full Text PDFCrystal structures of two formamidinium hexa-fluorido-phosphate salts, one with batch-dependent disorder.
Acta Crystallogr E Crystallogr Commun
January 2024
Department of Chemistry, Fordham University, 441 East Fordham Road, Bronx, NY 10458, USA.
Syntheses of the acyclic amidinium salts, morpholino-formamidinium hexa-fluorido-phosphate [OCHN-CH=NH]PF or CHNO·PF , , and pyrrolidinoformamidinium hexa-fluorido-phosphate [CHN-CH= NH]PF or CHN ·PF , , were carried out by heating either morpholine or pyrrolidine with triethyl orthoformate and ammonium hexa-fluorido-phosphate. Crystals of obtained directly from the reaction mixture contain one cation and one anion in the asymmetric unit. The structure involves cations linked in chains parallel to the axis by N-H⋯O hydrogen bonds in space group , with glide-related chains pointing in opposite directions.
View Article and Find Full Text PDF(2,2'-Bipyrid-yl)(η--cymene)iodidoruthenium(II) hexa-fluorido-phosphate.
IUCrdata
May 2023
Department of Chemical Sciences, University of Johannesburg, Auckland Park, Johannesburg 2006, South Africa.
The title compound, having the mol-ecular formula [RuI(η-CH)(CHN)]PF, crystallizes in the triclinic ( = 2) space group as a half-sandwich complex resembling a three-legged piano stool. Important geometrical parameters include Ru-cymene centroid = 1.6902 (17) Å, Ru-I = 2.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!