Proper management of fertigation is necessary to deal with the harmful impacts of fertilizers. This research aimed to investigate the nitrate leaching rate into groundwater in different fertigation management under the climate change impact in drip irrigation of corn. For this purpose, HYDRUS-2D was calibrated by performing field experiments. Plant water requirement and rainfall were projected until 2050 using LARS-WG6 under the RCP85 scenario. Then, nitrate leaching up to groundwater at the depth of 5 m was simulated in the growing season of corn and the like until 2050 in three fertigation scenarios, including S1 (three regional fertigation splits with irrigation efficiency of 85%), S2 (weekly fertigation with irrigation efficiency of 85%), and S3 (optimum fertigation with irrigation efficiency of 100%). Finally, the annual nitrate leaching rate to groundwater and leached amount were compared in the studied scenarios. The results demonstrated that nitrate penetrated to the depth of 117 and 105 cm at the end of the first year in S1 and S2 scenarios, respectively. In these scenarios, nitrate will reach groundwater in 2031, but nitrate concentrations will not be the same. In the S3 scenario, the nitrate will reach a depth of 180 cm by 2050. Total leached nitrate to groundwater up to 2050 will be 1740, 1200, and zero kg/ha in S1, S2, and S3 scenarios, respectively. Based on the approach of this study, the vulnerability of groundwater to nitrate contamination in different agricultural areas can be evaluated, and appropriate strategies with minimum environmental impacts of fertilizer abuse can be selected accordingly.
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http://dx.doi.org/10.1007/s10653-023-01629-1 | DOI Listing |
Environ Sci Process Impacts
January 2025
Department of Civil and Environmental Engineering, University of Pittsburgh, Pittsburgh, PA, USA.
Conventional practices for inorganic nitrogen fertilizer are highly inefficient leading to excess nitrogen in the environment. Excess environmental nitrogen induces ecological (, hypoxia, eutrophication) and public health (, nitrate contaminated drinking water) consequences, motivating adoption of management strategies to improve fertilizer use efficiency. Yet, how to limit the environmental impacts from inorganic nitrogen fertilizer while maintaining crop yields is a persistent challenge.
View Article and Find Full Text PDFRSC Adv
January 2025
School of Chemistry and Chemical Engineering, Shanxi University Taiyuan 030006 China
Ionic liquid (IL) units in heterogeneous catalysts exhibit synergistic effects to enhance catalytic performance and stabilize catalytically active centers, while also preventing the degradation of catalysts during the reaction process. Ionic liquid units in IL-functionalized CMOF catalysts enhance their catalytic performance in a synergistic manner. However, not only are the yields of IL-functionalized CMOFs obtained with post-synthesis methods low, but they also lead to blocking of the MOF pores and leaching of the ionic liquid.
View Article and Find Full Text PDFJ Contam Hydrol
December 2024
Institute of Surface-Earth System Science, School of Earth System Science, Tianjin University, Tianjin 300072, China.
Frequent exchange of surface water and groundwater in karst agricultural areas results in soil nutrient loss during rainfall and consequent deterioration of the aquatic environment. To understand nitrogen (N) transformation and leaching processes from karst soil during rainfall events, two typical N fertilizers were added to karst soil and consequently investigated the nitrogenous species using soil column experiments system. The contents of various N forms in the soil and leachate were analyzed, and the net nitrification and the N leaching rates were calculated.
View Article and Find Full Text PDFSci Rep
December 2024
Nuclear Fuel Cycle Research School, Nuclear Science and Technology Research Institute, P.O. Box: 11365-8486, Tehran, Iran.
This study describes the use of the emulsion liquid membrane (ELM) technique to recover thorium (Th(IV)) from an aqueous nitrate solution. The components of the ELM were kerosene as a diluent, sorbitan monooleate (span 80) as a surfactant, bis(2,4,4-trimethylpentyl)phosphinic acid (Cyanex 272) as an extractant, and HSO solution as a stripping reagent. Th(IV) was more successfully extracted and separated under the following favorable conditions: Cyanex272 concentration of 0.
View Article and Find Full Text PDFJ Environ Qual
December 2024
USDA-ARS National Laboratory for Agriculture and the Environment, Ames, Iowa, USA.
Nutrient losses via subsurface tile cause environmental degradation of aquatic ecosystems. Various management practices are primarily aimed at reduction of nitrate leaching in tile discharge; however, studies on leaching of other nutrients are limited. A replicated plot experiment was initiated in 2016 as part of the Long-Term Agroecosystem Research (LTAR) network Croplands Common Experiment to quantify the effectiveness of management practices on leaching of NO-N, total P, K, and S from drained soils.
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