A new isopolyoxotungstate has been characterised, thirty years since the first spectroscopic evidence of its existence. The heptatungstate [WOH], containing a {W} lacunary Lindqvist unit fused to a ditungstate fragment, has significant stability and is only the third isopolytungstate structure to be obtained from non-aqueous systems.
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A thirty-year old mystery solved: identification of a new heptatungstate from non-aqueous solutions.
Chem Commun (Camb)
June 2023
Chemistry, School of Natural & Environmental Sciences, Newcastle University, Newcastle upon Tyne, NE1 7RU, UK.
A new isopolyoxotungstate has been characterised, thirty years since the first spectroscopic evidence of its existence. The heptatungstate [WOH], containing a {W} lacunary Lindqvist unit fused to a ditungstate fragment, has significant stability and is only the third isopolytungstate structure to be obtained from non-aqueous systems.
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