A photoredox-mediated radical amidation ring-expansion sequence that enables the generation of all-carbon quaternary centers bearing a protected aminomethyl substituent is described. The methodology can be applied to both styrene and unactivated alkene substrates generating structurally diverse sp -rich amine derivatives in a concise manner.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC10947466 | PMC |
| http://dx.doi.org/10.1002/chem.202300922 | DOI Listing |
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