A new method based on selective fluorescent polymers (PSresin) for the analysis of Sr in presence of Pb in environmental samples.

Appl Radiat Isot

Departament d'Enginyeria Química i Química Analítica, Universitat de Barcelona, Marti i Franqués, 1-11, ES, 08028, Barcelona, Spain; Serra-Húnter Programme, Generalitat de Catalunya, Barcelona, Spain; Institut de Recerca de l'Aigua, Universitat de Barcelona, Spain. Electronic address:

Published: September 2023

Sr is of major concern in emergency and environmental control plans. It is one of the main fission products in nuclear facilities and is a high-energy beta emitter that presents chemical properties similar to those of calcium. Sr is commonly detected using methods based on liquid scintillation counting (LSC) following a chemical separation to remove potential interferences. However, these methods generate mixed wastes (hazardous and radioactive). In recent years, an alternative strategy using PSresins has been developed. For Sr analysis with PSresins, Pb is the main interferent that should be considered, as it is also strongly retained in the PSresin. In this study, a procedure was developed involving a precipitation with iodates to separate lead from strontium before the PSresin separation. Moreover, the method developed was compared with well-established and routinely used methods based on LSC, revealing that the new method produced equivalent results in less time and with less waste generation.

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http://dx.doi.org/10.1016/j.apradiso.2023.110879DOI Listing

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