Wide bandgap semiconductors such as gallium oxide (GaO) have attracted much attention for their use in next-generation high-power electronics. Although single-crystal GaO substrates can be routinely grown from melt along various orientations, the influence of such orientations has been seldom reported. Further, making rectifying p-n diodes from GaO has been difficult due to lack of p-type doping. In this study, we fabricated and optimized 2D/3D vertical diodes on β-GaO by varying the following three factors: substrate planar orientation, choice of 2D material and metal contacts. The quality of our devices was validated using high-temperature dependent measurements, atomic-force microscopy (AFM) techniques and technology computer-aided design (TCAD) simulations. Our findings suggest that 2D/3D β-GaO vertical heterojunctions are optimized by substrate planar orientation (-201), combined with 2D WS exfoliated layers and Ti contacts, and show record rectification ratios (>10) concurrently with ON-Current density (>10 A cm) for application in power rectifiers.
Download full-text PDF |
Source |
---|---|
http://dx.doi.org/10.1039/d3nr01987j | DOI Listing |
Micromachines (Basel)
December 2024
Tianmushan Laboratory, Yuhang District, Hangzhou 311115, China.
The continuous expansion of wireless communication application scenarios demands the active tuning of electromagnetic (EM) metamaterials, which is essential for their flexible adaptation to complex EM environments. However, EM reconfigurable systems based on intricate designs and smart materials often exhibit limited flexibility and incur high manufacturing costs. Inspired by mechanical metastructures capable of switching between multistable configurations under repeated deformation, we propose a planar kirigami frequency selective surface (FSS) that enables mechanical control of its resonant frequency.
View Article and Find Full Text PDFMicromachines (Basel)
November 2024
Instituto Nacional de Astrofísica, Óptica y Electrónica-INAOE, Puebla 72840, Mexico.
This work presents the design, fabrication, and rigorous validation of a flexible, wireless, capacitive pressure sensor for the full-range continuous monitoring of ventricular pressure. The proposed system consists of an implantable set and an external readout device; both modules were designed to form an RCL resonant circuit for passive, wireless pressure sensing and signal retrieving. Using surface micromachining and flexible electronics techniques, a two-variable capacitor array and a dual-layer planar coil were integrated into a flexible ergonomic substrate, avoiding hybrid-like connections in the implantable set.
View Article and Find Full Text PDFOrg Lett
December 2024
State Key Laboratory of Chemical Biology, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences (CAS), CAS, Shanghai 200032, China.
Rearrangement of the skeleton is crucial for improving the structural complexity and diversity of type II polyketide natural products. In this study, we investigated the rearrangement process from a planar aromatic tetracyclic intermediate to the caged lactones, which is managed by five oxidoreductases. We chemically synthesized the proposed linear tetracyclic substrate, validated the transformation process through and experiments, and elucidated the enzyme-catalyzed mechanism using isotope labeling.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
Smith School of Chemical and Biomolecular Engineering, Cornell University, Ithaca, New York 14853, United States.
Liquid crystals (LCs), when interfaced with chemically functionalized surfaces, can amplify a range of chemical and physical transformations into optical outputs. While metal cation-binding sites on surfaces have been shown to provide a basis for the design of chemoresponsive LCs, the cations have been found to dissociate from the surfaces and dissolve slowly into LCs, resulting in time-dependent changes in the properties of LC-solid interfaces (which impacts the reliability of devices incorporating such surfaces). Here, we explore the use of surfaces comprising metal-coordinating polymers to minimize the dissolution of metal cations into LCs and characterize the impact of the interfacial environment created by the coordinating polymer on the ordering and time-dependent properties of LCs.
View Article and Find Full Text PDFAppl Phys Lett
January 2024
Communications Technology Laboratory, National Institute of Standards and Technology, 325 Broadway, Boulder, Colorado 80305, USA.
Fused silica has become an interesting alternative to silicon for millimeter-wave (mmWave) applications. Unfortunately, there are a few reports on the measurement of fused silica's permittivity above 110 GHz that use electrical rather than optical methods. Given that mmWave applications use electrical circuits, additional electrical data would be useful to industry.
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!