Department of Chemistry, Omidiyeh Branch, Islamic Azad University, Omidiyeh, 6373193719, Iran.
Published: August 2023
AI Article Synopsis
Article Abstract
β-cyclodextrin (CD) was grafted with multi-walled carbon nanotubes/chitosan (MWCNTs/Cs) to obtain MWCNTs/Cs/CD nanocomposite (NC) for methylene blue (MB) adsorption from aqueous media. TEM, XRD, TGA, Raman spectra, and BET & BJH analyses were utilized to characterize and confirm the successful synthesis of as-prepared NC. MB capture was investigated by considering the parameters of pH (1.9-9.0), temperature (∼16-63 °C), sonication time (∼5-15 min), MB concentration (∼1.2-48 mg/L), and NC dose (0.03-0.26 mg). The obtained responses were then modelled using CCD, generalized regression neural network (GRNN), and least squares support vector machine (LS-SVM), of which the latter found to provide most reliable and accurate results (RMSE = 0.0235, MAE = 0.020, AAD = 0.0047, and R = 0.999). Moreover, the genetic algorithm-based optimization results showed that under the respective values of 7.05, 45.5 °C, 10 min, 23 mg/L, 0.12 g, MWCNTs/Cs/CD NC would be able to remove 96.75% of MB with an adsorption capacity of 603 mg/g, through different mechanisms mainly electrostatic interactions. Following from Dubinin-Radushkevich (D-R) isotherm (q = 460.66 ± 8.9 and R > 0.99) and intraparticle diffusion kinetic (R = 0.75-0.90) models indicated a chemical adsorption mechanism. Besides, thermodynamic parameters (ΔH◦ = -66.9 kJ/mol, ΔG◦ = between -3.77 kJ/mol and -8.52 kJ/mol, and ΔS◦ = 237.1818 J/mol K) confirmed an endothermic and spontaneous nature for the adsorption. These findings along with appropriate recyclability (five times), turn the as prepared NC to a promising material in removing MB from aqueous solutions.
Immune reactions to medical implants often lead to encapsulation by fibrotic tissue and impaired device function. This process is thought to initiate by protein adsorption, which enables immune cells to attach and mount an inflammatory response. Previously, several antifibrotic materials have been either designed to reduce protein adsorption or discovered via high-throughput screens (HTS) to favorably regulate inflammation.
Background: Multiple and complicated hepatolithiasis can be associated with decompensated cirrhosis. Endoscopic retrograde cholangiopancreatography is unavailable for multiple and complicated hepatolithiasis, and the mainstay for decompensated cirrhosis is liver transplantation. However, due to the ethical factors and the complexity of operation, liver transplantation cannot be widely operated.
Division of Hepatobiliary and Transplantation Surgery, Department of General Surgery, Nanjing Drum Tower Hospital, Affiliated Hospital of Medical School, Nanjing University, Nanjing, 210008, China.
Liver tissue engineering holds promising in synthesizing or regenerating livers, while the design of functional scaffold remains a challenge. Owing to the intricate simulation of extracellular matrix structure and performance, porous scaffolds have demonstrated advantages in creating liver microstructures and sustaining liver functions. Currently, various methods and processes have been employed to fabricate porous scaffolds, manipulating the properties and morphologies of materials to confer them with unique supportive functions.
Fast-charging lithium-ion batteries (LIBs) are the key to solving the range anxiety of electric vehicles. However, the lack of separators with high Li transportation rates has become a major bottleneck, restricting their development. In this work, the electrochemical performance of traditional polyethylene separators was enhanced by coating AlO nanoparticles with a novel green binder.
Hepato-Pancreato-Biliary Surgery and Liver Transplantation, Pôle des Pathologies Hépatiques et Digestives, Hôpital de Hautepierre-Hôpitaux Universitaires de Strasbourg, Université de Strasbourg, Strasbourg, France.
