Diazocines are azobenzene derived macrocyclic photoswitches with well resolved photostationary states for the ()- and ()-isomers, which improves their addressability by light. In this work, effective procedures for the stannylation and borylation of diazocines in different positions are reported. Their use in Stille cross-coupling and Suzuki cross-coupling reactions with organic bromides is demonstrated in yields of 47-94% (Stille cross-coupling) and 0-95% (Suzuki cross-coupling), respectively.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC10227463 | PMC |
| http://dx.doi.org/10.1039/d3ra02988c | DOI Listing |
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