The extended damp heat and thermal cycling tests were performed on unencapsulated flexible thin-film GaInP/GaAs/InGaAs solar cells to assess the long-term stability. The solar cells were subjected to 85 °C/85% damp heat test for more than 1000 h and 420 cycles of thermal cycling test between -60 °C and 75 °C, respectively. The performance attenuations of flexible solar cells were less than 2% in both cases, which were due to the slow decline of the open-circuit voltage with aging time. The slight decrease in open voltage was attributed to the increase in reverse saturation current due to the enhanced recombination, which was in good agreement with the calculation based on the two-diode model. The good performance of the unencapsulated flexible GaInP/GaAs/InGaAs solar cells in severe environment indicated the stable and reliable device fabrication art in the experiment.
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http://dx.doi.org/10.1016/j.heliyon.2023.e16462 | DOI Listing |
Angew Chem Int Ed Engl
January 2025
City University of Hong Kong, Chemistry, HONG KONG.
Achieving rational control over chemical and energetic properties at the perovskite/electron transport layer (ETL) interface is crucial for realizing highly efficient and stable next-generation inverted perovskite solar cells (PSCs). To address this, we developed multifunctional ferrocene (Fc)-based interlayers engineered to exhibit adjustable passivating and electrochemical characteristics. These interlayers are designed to minimize non-radiative recombination and, to modulate the work function (WF) and uniformity of the perovskite surface, thereby enhancing device performance.
View Article and Find Full Text PDFDiscov Nano
January 2025
Instituto de Ciencia de Materiales de Madrid, CSIC, Cantoblanco, 28049, Madrid, Spain.
Chemically tuned organic-inorganic hybrid halide perovskites based on bromide and chloride anions CH(NH)Pb(BrCl) (CH(NH): formamidinium ion, FA) have been crystallized and investigated by neutron powder diffraction (NPD), single crystal X-ray diffraction (SCXRD), scanning electron microscopy (SEM) and UV-vis spectroscopy. FAPbBr and FAPbCl experience successive phase transitions upon cooling, lowering the symmetry from cubic to orthorhombic phases; however, these transitions are not observed for the mixed halide phases, probably due to compositional disorder. The band-gap engineering brought about by the chemical doping of FAPb (BrCl) perovskites (x = 0.
View Article and Find Full Text PDFACS Mater Au
January 2025
State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Materials Science and Engineering, Donghua University, Shanghai 201620, P. R. China.
The integration of fluorinated benzothiadiazole (FBT) into donor-acceptor (D-A) copolymers represents a major advancement in the field of organic solar cells (OSCs). The fluorination process effectively fine-tunes the energy levels, reduces the highest occupied molecular orbital levels, and enhances the open-circuit voltages of the polymers. Furthermore, fluorination improves molecular packing and crystallinity, which significantly boosts the charge transport and overall device performance.
View Article and Find Full Text PDFHeliyon
January 2025
Grupo de Investigación en Fotoquímica y Fotobiología, Programa de Química, Facultad de Ciencias Básicas, Universidad Del Atlántico, Puerto Colombia, 81007, Colombia.
Since Dye-Sensitized Solar Cells (DSSCs) was created, a versatile and cost-effective alternative among photovoltaic technology options for power generation and energy transition to combat climate change have emerged. The theoretical and experimental knowledge of DSSCs have increased in regard to their operation in the last three decades of development; it includes the device's components, as well as the most recent innovations in their application and forms of activation. In this work paper, we presented a meta-study of photovoltaic characterization parameters, 329 scientific reports of DSSCs were considered to compare three types of sensitizers (Organometallics, non-metal organic dyes and, natural dyes).
View Article and Find Full Text PDFJ Phys Chem Lett
January 2025
State Key Laboratory of Reliability and Intelligence of Electrical Equipment, School of Materials Science and Engineering, Hebei University of Technology, Tianjin 300401, China.
A significant barrier to the commercialization of solution-processed perovskite solar cells (PSCs) is the chemical instability of the components in precursor solutions under ambient conditions. This instability leads to solution aging, which subsequently diminishes the quality and reproducibility of the resulting PSCs. Inspired by recent published works, which focused on the deprotonation of organic cations, the oxidation of iodide, and the formation of undesired byproducts, we here systematically summarize and provide an outlook on the research directions and perspectives of the origin of precursor solution aging and countermeasures, such as using stabilizing additives, redox shuttles, Schiff base reactions, and green solvents.
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