The well-defined iron(0) complex [(DPB)Fe-(μ-1,2-N)] (A) reacts with HBpin to afford the complex [(-HDPB)Fe(-HBpin)] (B) oxidative addition of the H-B bond. Complex A is an effective pre-catalyst for the hydroboration of a range of olefins in synthetically useful yields (typically >80%) under neat conditions.
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