Polyaniline-co-polyindole functionalized magnetic porous carbon derived from MIL-53(Fe) for separation/enrichment of nitrophenols pollutants before determination with high-performance liquid chromatography-ultraviolet detection.

Herein, a novel polyaniline-co-polyindole functionalized magnetic porous carbon derived from MIL-53(Fe) was prepared and employed as an excellent nano-adsorbent to preconcentrate trace amounts of nitro-phenols in water and wastewater samples. Briefly, magnetic MIL-53(Fe) was synthesized by the addition of magnetite nanoparticles, terephthalic acid, and FeCl to the reaction medium. The magnetic MIL-53(Fe) was pyrolyzed under nitrogen protection to obtain a magnetic porous carbon nanocomposite, and finally, the nanomaterial was functionalized with polyaniline-co-polyindole via oxidation polymerization. The obtained nano-adsorbent was characterized via X-ray diffraction, Fourier-transform infrared spectroscopy, vibrating sample magnetometry, and transmission and scanning electron microscopies. After that, the fabricated nano-material was utilized as an excellent nano-adsorbent for the preconcentration of trace nitro-phenols (2-nitrophenol, 4-nitrophenol, and 2,4-dinitrophenol) in environmental water, and wastewater samples. The detection limits were obtained from 0.1 to 0.15 μg/L after performing the optimization process. The new method was in the range of 0.4-300 μg/L. The proposed method exhibited a good precision from 3.2% to 9.6% for within-day assay, and 5.2%-13.2% for between-day assay at three concentration levels (1, 50, and 250 μg/L). Eventually, this method was utilized to preconcentrate/determine the target analytes in three water, and wastewater samples, satisfactory (relative standard deviations, 5.4%-9.3%; relative recovery, 88%-109%).