To solve the issue of the poor temperature stability of conventional modified asphalt, polyurethane (PU) was used as a modifier with its corresponding curing agent (CA) to prepare thermosetting PU asphalt. First, the modifying effects of the different types of PU modifiers were evaluated, and the optimal PU modifier was then selected. Second, a three-factor and three-level L9 (3) orthogonal experiment table was designed based on the preparation technology, PU dosage, and CA dosage to prepare the thermosetting PU asphalt and asphalt mixture. Further, the effect of PU dosage, CA dosage, and preparation technology on the 3d, 5d, and 7d splitting tensile strength, freeze-thaw splitting strength, and tensile strength ratio (TSR) of the PU asphalt mixture was analyzed, and a PU-modified asphalt preparation plan was recommended. Finally, a tension test was conducted on the PU-modified asphalt and a split tensile test was performed on the PU asphalt mixture to analyze their mechanical properties. The results show that the content of PU has a significant effect on the splitting tensile strength of PU asphalt mixtures. When the content of the PU modifier is 56.64% and the content of CA is 3.58%, the performance of the PU-modified asphalt and mixture is better when prepared by the prefabricated method. The PU-modified asphalt and mixture have high strength and plastic deformation ability. The modified asphalt mixture has excellent tensile performance, low-temperature performance, and water stability, which meets the requirements of epoxy asphalt and the mixture standards.
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http://dx.doi.org/10.3390/polym15102327 | DOI Listing |
PLoS One
January 2025
Key Laboratory for Special Area Highway Engineering of Ministry of Education, Chang'an University, Xi'an, Shaanxi, China.
The large particle size asphalt mixture with nominal maximum aggregate size 53 mm(LSAM-50) has good technical and economic performance and will become an effective technical way to build a full-thick long-life asphalt pavement with Chinese characteristics. In order to reveal the mechanical properties and influencing factors of LSAM-50 in depth, a numerical test method for the mechanical properties of the large particle size LSAM-50 asphalt mixture was developed, and a reasonable specimen size for LSAM-50 performance test was proposed by combining the numerical test and the indoor test. The results show that: LSAM-50 numerical test conditions are the calculation time step 10-3 s/step, the loading rate is 2 mm/min (uniaxial compression numerical test) and 50 mm/min (splitting numerical test) when LSAM-50 numerical experiment calculation rate and numerical experiment accuracy are better; after the size of the specimen reaches 200×160mm, the influence of the size effect is eliminated.
View Article and Find Full Text PDFMaterials (Basel)
January 2025
College of Civil Engineering and Architecture, Shandong University of Science and Technology, Qingdao 266590, China.
To investigate the water damage at the interface between emulsified asphalt and aggregate under the action of external water infiltration, firstly, cetyltrimethylammonium bromide was used as an emulsifier to prepare emulsified asphalt in the laboratory, and its basic properties were tested. Then, based on molecular dynamics, an emulsified asphalt-aggregate interface model with different water contents was constructed to calculate the adhesion work of the emulsified asphalt-aggregate interface. The results show that the simulated values of emulsified asphalt density, cohesive energy density, and solubility are in good agreement with the experimental values.
View Article and Find Full Text PDFMaterials (Basel)
January 2025
College of Engineering, Zhejiang Normal University, Jinhua 321004, China.
Asphalt pavement, widely utilized in transportation infrastructure due to its favourable properties, faces significant degradation from chloride salt erosion in coastal areas and winter deicing regions. In this study, two commonly used asphalt binders, 70# base asphalt and SBS (Styrene-Butadiene-Styrene)-modified asphalt, were utilized to study the chloride salt erosion effect on asphalt pavement by immersing materials in laboratory-prepared chloride salt solutions. The conventional properties and adhesion of asphalt were assessed using penetration, softening point, ductility, and pull-off tests, while Fourier transform infrared spectroscopy (FTIR) elucidated the erosion mechanism.
View Article and Find Full Text PDFMaterials (Basel)
December 2024
College of Civil Science and Engineering, Yangzhou University, Yangzhou 225100, China.
Polymers (Basel)
December 2024
Faculty of Civil Engineering, Nguyen Tat Thanh University, 300A Nguyen Tat Thanh Street, District 4, Ho Chi Minh City 700000, Vietnam.
The increasing demand for sustainable construction materials has driven the exploration of alternative fillers in asphalt production. Traditional asphalt mixtures rely heavily on natural aggregates and petroleum-based binders, contributing to environmental degradation. This study proposes an innovative solution by utilizing Crushed Recycled Marble Stone Powder (CRMSP) as a sustainable filler in SBS polymer-modified asphalt containing high volumes of recycled tire rubber, addressing both resource depletion and waste management concerns.
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