The recycling of spent lithium-ion batteries (LIBs) has attracted great attention, mainly because of its significant impact on resource recycling and environmental protection. Currently, the processes involved in recovering valuable metals from spent LIBs have shown remarkable progress, but little attention has been paid to the effective separation of spent cathode and anode materials. Significantly, it not only can reduce the difficulty in the subsequent processing of spent cathode materials, but also contribute to the recovery of graphite. Considering the difference in their chemical properties on the surface, flotation is an effective method to separate materials, owing to its low-cost and eco-friendly characteristics. In this paper, the chemical principles of flotation separation for spent cathodes and materials from spent LIBs is summarized first. Then, the research progress in flotation separation of various spent cathode materials (LiCoO, LiNiCoMnO, and LiFePO) and graphite is summarized. Given this, the work is expected to offer the significant reviews and insights about the flotation separation for high-value recycling of spent LIBs.
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http://dx.doi.org/10.3390/molecules28104081 | DOI Listing |
Langmuir
January 2025
Key Laboratory of Green Utilization of Critical Non-Metallic Mineral Resources of Ministry of Education, Wuhan University of Technology, Wuhan 430070, China.
Reverse flotation separation of muscovite from apatite using a dodecylpyridinium chloride (DPDC) ionic liquid as the collector was studied in this work. The microflotation results depicted that DPDC had a strong collecting for muscovite but had a slight collecting for apatite when using phosphoric acid as a depressant for apatite in a weakly acidic pH value pulp, artificial mixture mineral flotation showed that reverse flotation separation of muscovite from apatite can be effectively achieved in the reagent scheme of phosphoric acid/DPDC, and DPDC had a better separation performance in the muscovite/apatite system than DDA. The adsorption measurements indicated that the adsorption amount of DPDC on the apatite surface was less than that of DPDC on the muscovite surface, and the zeta potential results confirmed that a strong interaction occurred between DPDC and the muscovite surface, while an extremely weak interaction occurred between DPDC and the apatite surface in the presence of phosphoric acid at pH ∼ 5.
View Article and Find Full Text PDFToxics
December 2024
School of Resource and Environmental Engineering, Shandong University of Technology, Zibo 255000, China.
The solid phase composition in oily sludge (OS) is a key factor affecting the oil-solid separation of OS. In this paper, the effects and mechanisms of solid-phase particle factors on the oil content of residue phase were investigated in order to improve the oil-solid separation efficiency. Flotation experiments were carried out on single-size sand and mixed-size sand OS consisting of three particle sizes at room temperature without adding flotation reagents.
View Article and Find Full Text PDFMolecules
December 2024
Faculty of Land Resources Engineering, Kunming University of Science and Technology, Kunming 650093, China.
The increasing demand for zinc resources and the declining availability of sulfide zinc ore reserves have made the efficient utilization of zinc oxide a topic of considerable interest. In this study, a ternary composite collector ABN (Al-BHA-NaOL system) was applied to the direct flotation of smithsonite. Micro-flotation studies showed that at pH 9, ABN exhibited better adsorption on smithsonite, achieving a recovery rate of 80.
View Article and Find Full Text PDFMaterials (Basel)
December 2024
Faculty of Technology and Metallurgy, University of Belgrade, Karnegijeva 4, 11120 Belgrade, Serbia.
Copper flotation tailings (FTs), resulting from the separation and beneficiation processes of ores, are a significant source of environmental pollution (acid mine drainage, toxic elements leaching, and dust generation). The most common disposal method for this industrial waste is dumping. However, due to their favorable physical and chemical properties-the high content of aluminosilicate minerals (60-90%)-flotation tailings can be effectively treated and reused through geopolymerization technology, thereby adding value to this waste.
View Article and Find Full Text PDFEnviron Res
December 2024
College of Environmental Science and Engineering, Qingdao University, Qingdao, China. Electronic address:
Microplastics (MPs) recycling, a promising approach to tackle its pollution, faces significant challenges due to the lack of effective separation methods. Herein, the optimized density separation accompanied with nonionic surfactants was employed to purify single MPs species from mixed systems. By adjusting the flotation fluid density, the single MPs can be separated from their mixtures in equal proportions (e.
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