Multicomponent materials are microwave-absorbing (MA) materials composed of a variety of absorbents that are capable of reaching the property inaccessible for a single component. Discovering mostly valuable properties, however, often relies on semi-experience, as conventional multicomponent MA materials' design rules alone often fail in high-dimensional design spaces. Therefore, we propose performance optimization engineering to accelerate the design of multicomponent MA materials with desired performance in a practically infinite design space based on very sparse data. Our approach works as a closed-loop, integrating machine learning with the expanded Maxwell-Garnett model, electromagnetic calculations, and experimental feedback; aiming at different desired performances, Ni surface@carbon fiber (NiF) materials and NiF-based multicomponent (NMC) materials with target MA performance were screened and identified out of nearly infinite possible designs. The designed NiF and NMC fulfilled the requirements for the X- and Ku-bands at thicknesses of only 2.0 and 1.78 mm, respectively. In addition, the targets regarding S, C, and all bands (2.0-18.0 GHz) were also achieved as expected. This performance optimization engineering opens up a unique and effective way to design microwave-absorbing materials for practical application.
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http://dx.doi.org/10.1021/acsami.3c02794 | DOI Listing |
Magn Reson Med
March 2025
Center for Magnetic Resonance Research, Radiology, Medical School, University of Minnesota, Minneapolis, Minnesota, USA.
Purpose: To propose a two-step, nonlocal principal component analysis (PCA) method and demonstrate its utility for denoising complex diffusion MR images with a few diffusion directions.
Methods: A two-step denoising pipeline was implemented to ensure accurate patch selection even with high noise levels and was coupled with data preprocessing for g-factor normalization and phase stabilization before data denoising with a nonlocal PCA algorithm. At the heart of our proposed pipeline was the use of a data-driven optimal shrinkage algorithm to manipulate the singular values in a way that would optimally estimate the noise-free signal.
Anal Methods
March 2025
Departamento de Química, Instituto para el Desarrollo Agroindustrial y de la Salud (IDAS), Facultad de Ciencias Exactas, Físico-Químicas y Naturales, Universidad Nacional de Río Cuarto, Rio Cuarto 5800, Argentina.
Neonicotinoids are systemic insecticides used in agriculture. In particular, imidacloprid (IM) and thiamethoxam (TM) have selective toxicity to insects, and they have been implicated in the steep decline of the global honeybee population, specifically in colony collapse disorder (CCD). Some scientific reports have shown that a significant amount of honey worldwide contains traces of neonicotinoids, at levels strong enough to cause damage to bees.
View Article and Find Full Text PDFPhys Chem Chem Phys
March 2025
School of Micro-Nano Electronics, Zhejiang University, Hangzhou, 310027, China.
Proposing an effective modification strategy to optimize catalyst reaction potentials is crucial for enhancing catalytic performance. In this study, we employed a combined approach by adjusting nitrogen dopants in the first- and second-shell environments to tailor the OER/ORR reaction potentials of FeN, CoN, and NiN active centers. Using density functional theory simulations, we systematically compared the effects of first- and second-shell nitrogen dopants on the local atomic/electronic structures and catalytic activities.
View Article and Find Full Text PDFProton insertion mechanism with fast reaction kinetics is attracting more and more attention for high-rate and durable aqueous Zn─MnO batteries. However, hydrated Zn insertion reaction accompanied with Jahn-Teller effect and Mn disproportionation generally leads to sluggish rate capability and irreversible structure transformation. Here, carboxyl-carbon nanotubes supported α-MnO nanoarrays (C─MnO) cathode is successfully fabricated by a convent grinding process for high-performance Zn batteries.
View Article and Find Full Text PDFACS Appl Mater Interfaces
March 2025
Department of Chemistry, National Tsing Hua University, Hsinchu 300044, Taiwan.
To further demonstrate semiconductor facet effect to photocatalytic organic transformations and address a lack of using simple polyhedral semiconductor particles for disulfide bond formation, CuO cubes, octahedra, and rhombic dodecahedra were used to photocatalyze aerobic oxidation of 4-methylbenzenethiol. After reaction condition optimization, CuO crystals and ,,','-tetramethylethylenediamine (TMEDA) were added to 4-methylbenzenethiol in ethanol for thiol oxidation to 1,2-di--tolyldisulfane under 390 nm light-emitting diode (LED) lamp irradiation for just 5 min. Rhombic dodecahedra gave the highest product yield, followed by octahedra, cubes, and commercial CuO powder.
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