Speciation of Phosphorus in Pet Foods by Solid-State P-MAS-NMR Spectroscopy.

J Agric Food Chem

Nuclear Magnetic Resonance Facility, University of California at Davis, Davis, California 95616, United States.

Published: June 2023

Solid-state magic angle spinning P NMR spectroscopy is used to identify and quantify phosphorus-containing species in pet foods. The measurement is challenging due to the long spin-lattice relaxation times (s). Data acquisition times are shortened by acquiring data with a tip angle smaller than 90° and shortening the repetition time. However, the spin-lattice relaxation times (s) of the different P compounds are quite different, necessitating a separate measurement for each compound in the pet food. Knowledge of is used to calculate the relative amount of P in the samples. Samples of known concentration are also measured, enabling the quantitative measurement of total phosphorus content.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC10251508PMC
http://dx.doi.org/10.1021/acs.jafc.2c07339DOI Listing

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